Cleavage of the etheric bond in cyclopentadienyliron ...



Title Cleavage of the etheric bond in cyclopentadienyliron phenolphthalein complexes.
Author(s) Alaa S. Abd-El-Aziz, Shelly A. Bernardin, Khanh Tran
Journal Tetrahedron Letters, Tetrahedron letters
Date 1999
Volume 40
Issue 10
Start page 1835
End page 1838
Abstract The reaction of aliphatic primary amines with phenolphthalein-containing dicyclopentadienyliron complexes led to etheric bond cleavage. This unique cleavage reaction is due to nucleophilic attack by the amines ipso to the etheric group of the complexed arene, which is activated by coordination to the cationic cyclopentadienyliron moiety.
DOI 10.1016/S0040-4039(99)00081-7

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