A convenient synthesis of some arylated ...
|Title||A convenient synthesis of some arylated phenylsulfonylacetonitriles and ethyl cyanoacetates using organoiron complexes.|
|Author(s)||A. Abd-El-Aziz, C. De Denus|
|Journal||Section Title: Benzene, Its Derivatives, and Condensed Benzenoid Compounds, Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999)|
|Abstract||Arylated phenylsulfonylacetonitriles, e.g., PhCH(CN)SO2Ph, and Et cyanoacetates, e.g., PhCH(CN)CO2Et, were prepd. by nucleophilic substitution of cyclopentadienyliron complexes of chloroarenes, e.g., I, with NCCH2R (R = SO2Ph, CO2Et) in the presence of potassium carbonate in DMF followed by photolysis. This synthesis is advantageous over all those previously reported and should be a practical route to a variety of alkanoic acid and heterocyclic precursors. [on SciFinder(R)]|
Using APA 6th Edition citation style.
Times viewed: 71