Synthesis of Isomeric Ethyl Tolylcyanoacetates Using ...



Title Synthesis of Isomeric Ethyl Tolylcyanoacetates Using Organo-Iron Complexes
Author(s) Alaa S. Abd-El-Aziz, Christine R. De Denus
Journal Synthetic Communications,
Date 1992
Volume 22
Issue 4
Start page 581
End page 591
Abstract Nucleophilic aromatic substitution of isomeric chlorotoluenes complexed to the cyclopentadienyliron moiety with ethyl cyanoacetate in the presence of K2CO3 in DMF results in the formation of the isomeric ethyl tolylcyanoacetate complexes. Photolysis of these complexes leads to the formation of the title compounds in high yields.
DOI 10.1080/00397919208019257

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