The first example of multiple oxidation reactions of ...
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| Title | The first example of multiple oxidation reactions of η6-alkylated aniline-η5-cyclopentadienyliron complexes. |
| Author(s) | A. Abd-el-Aziz, K. Epp |
| Journal | Section Title: Organometallic and Organometalloidal Compounds, Polyhedron |
| Date | 1995 |
| Volume | 14 |
| Issue | 7 |
| Start page | 957 |
| End page | 960 |
| Abstract | A unique synthetic route to cyclopentadienyliron complexes of functionalized nitrobenzene,e.g., I (e.g., R = Et),was developed via the successive oxidn. of the amine and the alkyl groups of their corresponding aniline complexes utilizing hydrogen peroxide. Nucleophilic arom. substitution reactions of the nitroarene iron complexes I (e.g., R = CHMe2) with a no. of nucleophiles, e.g., PhSO2CH2CN and HS(CH2)6SH, gave rise to monoiron II and diiron complexes III, resp., with various alkyl and keto substituents. [on SciFinder(R)] |
| DOI | 10.1016/0277-5387(94)00496-2 |
| ISSN | 0277-5387 |
Using APA 6th Edition citation style.
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