Arylation of diethyl malonate via nucleophilic ...



Title Arylation of diethyl malonate via nucleophilic substitution reactions with cyclopentadienyliron complexes of chloroarenes.
Author(s) Alaa S. Abd-El-Aziz, Choi Chuck Lee, Adam Piorko, Ronald G. Sutherland
Journal Synthetic Communications,
Date 1988
Volume 18
Issue 3
Start page 291
End page 300
Abstract Reaction of an η6-chloroarene-η5-cyclopentadienyl-iron hexafluorophosphate with diethyl malonate in the presence of K2CO3 in THF/DMSO gave a corresponding SN-Ar product, η6-diethyl arylmalonate-η5-cyclopentadienyliron hexafluorophosphate, which, upon pyrolytic sublimation, resulted in the liberation of the arylated malonic ester. Such esters prepared in the present work included RPhCH(COOEt)2, with R = o-, m- or p-CH3, 2,6-(CH3)2, or o-, m- or p-Cl2.
DOI 10.1080/00397918808057836

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