Benzo[f]- and benzo[h]coumarin-containing ...

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Title Benzo[f]- and benzo[h]coumarin-containing poly(methyl methacrylate)s and poly(methyl methacrylate)s with pendant coumarin-containing azo dyes.
Author(s) Alaa S. Abd-El-Aziz, Patrick O. Shipman, Edward G. Neeland, T. Christopher Corkery, Shawkat Mohammed, Pierre D. Harvey, Hany M. Mohamed, Ahmed H. Bedair, Ahmed M. El-Agrody, Pedro M. Aguiar, Scott Kroeker
Journal Macromolecular Chemistry and Physics,
Date 2008
Volume 209
Issue 1
Start page 84
End page 103
Abstract A series of coumarins were reacted with methacrylate or styrene derivs. to form new olefinic coumarin monomers that were polymd. using 2,2'-azobisisobutyronitrile. These polymers were highly insol. in org. solvents and displayed good thermal stability with glass-transition temps. 70-130°. Luminescence studies on some of the coumarin-contg. polymers showed some fluorescence (ΦF around 0.1). Some of the newly prepd. coumarins and benzocoumarins were reacted with azo dyes to form mixed coumarin-azo dye monomer precursors. These compds. were further reacted to prep. acrylic monomers which were then polymd.
DOI 10.1002/macp.200700476

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