A novel approach to the synthesis of some ...

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Title A novel approach to the synthesis of some 2-arylalkanoic acid esters.
Author(s) A. Abd-El-Aziz, S. Tesfalidet, C. de Denus, K. Lezynska
Journal Section Title: Benzene, Its Derivatives, and Condensed Benzenoid Compounds, Synthetic Communications
Date 1993
Volume 23
Issue 10
Start page 1415
End page 1426
Abstract A novel route to the synthesis of some 2-arylalkanoic acid esters has been achieved. Arom. nucleophilic substitution of various arenecyclopentadienyliron complexes, e.g., I (R = Cl, R1 = H, 3-, 4-Me) with Et ethylacetoacetate and Et methylacetoacetate produced the alkanoic acid ester complexes I (R = CHR2CO2Et, R2 = Me, Et). Photolysis of these complexes resulted in the liberation of the free esters II in good yields. [on SciFinder(R)]
DOI 10.1080/00397919308011231
ISSN 0039-7911

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