Organoiron polymers.
Description
Citation
| Title | Organoiron polymers. |
| Author(s) | A. Abd-El-Aziz, E. Todd |
| Journal | Section Title: Chemistry of Synthetic High Polymers, Coordination Chemistry Reviews |
| Date | 2003 |
| Volume | 246 |
| Issue | 1-2 |
| Start page | 3 |
| End page | 52 |
| Abstract | In this review, organoiron polymers are classified according to their structural make-up. The synthesis and characterization of oligomers and polymers contg. dienes and cyclobutadiene rings coordinated to iron tricarbonyl moieties are described. This is followed by a thorough investigation of ferrocene-based polymers. The ferrocenyl units are found in the polymer main and side chains, and a wide variety of these organoiron polymers and their properties are examd. Polymers contg. cyclopentadienyliron tricarbonyl complexes in their backbones and side chains are also described. Cationic η6-arene-η5-cyclopentadienyliron complexes have been incorporated into polymeric materials where the iron moieties are pendent to the main or side chains. The final class of organoiron polymers includes the iron-acetylides; these polymers are unique among the other examples described since the iron complexes are σ-bonded to the org. backbones of the polymers. [on SciFinder(R)] |
| DOI | 10.1016/S0010-8545(03)00107-3 |
Using APA 6th Edition citation style.
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