Design of iron- and ruthenium-containing polymers.



Paper title Design of iron- and ruthenium-containing polymers.
Paper author(s) Alaa S. Abd-El-Aziz, Erin K. Todd, Christine R. de Denus, Alexa A. Dembek, Paul J. Fagan
Proceedings title Book of Abstracts, 218th ACS National Meeting, New Orleans, Aug.22-26
Date 1999
Abstract A no. of sol. organometallic polymers with pendent cyclopentadienyliron and pentamethylcyclopentadienylruthenium moieties were prepd. under mild exptl. conditions. These polyarom. materials contained ether, thioether and amine bridges. The following figure represents one of the organometallic polymers with ether and amine bridges. These polymeric materials were characterized using NMR, GPC and thermogravimetric anal. Photolytic demetallation of the organometallic polymers allowed for the isolation of the purely org. polymers in good yield. Detailed exptl. conditions and properties of these materials will be presented. [on SciFinder(R)]

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