Synthesis of soluble polyethers and polythioethers ...



Paper title Synthesis of soluble polyethers and polythioethers with pendent cationic iron moieties.
Paper author(s) Alaa S. Abd-El-Aziz, Erin K. Todd, Karen M. Epp
Proceedings title Book of Abstracts, 215th ACS National Meeting, Dallas, March 29-April 2
Date 1998
Abstract Nucleophilic arom. substitution of p-dichlorobenzene complexed to a cyclopentadienyliron cation with oxygen and sulfur nucleophiles led to the formation of polymers with pendent iron moieties as shown in the following scheme. These polymers were sol. in various org. solvents. Photolytic demetallation was implemented to remove the metallic moieties from the backbone of the polymers. NMR and GPC were used to det. the structure of the org. polymers. [Equation Omitted]. [on SciFinder(R)]

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