Electrochemical investigations of oligomers and ...



Title Electrochemical investigations of oligomers and polymers containing ruthenium- and iron-arene complexes.
Author(s) Christine R. de Denus, Philip Baker, Jaclyn Toner, Sheila McKevitt, Erin K. Todd, Alaa S. Abd-El-Aziz
Journal Macromolecular Symposia,
Date 2003
Volume 196
Issue 1
Start page 113
End page 123
Abstract Cyclic voltammetry was employed to investigate the electrochemical behavior of numerous cyclopentadienyliron (CpFe+) and pentamethyl-cyclopentadienylruthenium (Cp*Ru+) coordinated oligomers and polymers. The electrochemical behavior of the iron systems indicated the cyclopentadienyliron complexes had isolated redox centers and that changes in the reversibility of the redox couple occurred with changes in solvent and temperature. In contrast, the monometallic ruthenium systems showed large peak separations that suggested slow kinetics on the CV timescale. The cyclic voltammograms of the larger ruthenium-containing oligomers and polymers showed multiple redox steps indicating complex electrochemical behavior.
DOI 10.1002/masy.200390152

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