Synthesis and characterization of the ring-opened ...

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Title Synthesis and characterization of the ring-opened copolymers of deltacyclene, 5-siloxydeltacyclene, and norbornene.
Author(s) M. Lautens, A. Abd-El-Aziz, C. Crudden
Journal Section Title: Chemistry of Synthetic High Polymers, Journal of Polymer Science, Part A: Polymer Chemistry
Date 1993
Volume 31
Issue 2
Start page 569
End page 574
Abstract The ring-opening metathesis copolymns. of deltacyclene (I), substituted I, and norbornene (II) was achieved using RuCl3, ReCl5, and Mo alkylidene catalysts. The reaction conditions employed are similar to those used previously in the syntheses of homopolymers. The low conversion copolymn. of I and II showed that I is more reactive than II by a factor of 2.4. The characterization and phys. properties of these copolymers were detd. using NMR, GPC, glass temp., and viscosity measurements. [on SciFinder(R)]
DOI 10.1002/pola.1993.080310230
ISSN 0887-624X

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