Preparation of cyclohexenyl derivatives by the ...
|Title||Preparation of cyclohexenyl derivatives by the ring-opening reactions of oxabicyclo[2.2.1] compounds with cuprates.|
|Author(s)||M. Lautens, A. Smith, A. Abd-El-Aziz, A. Huboux|
|Journal||Section Title: Alicyclic Compounds, Tetrahedron letters|
|Abstract||The ring-opening reaction of 7-oxabicyclo[2.2.1]hept-5-enes with cuprates is described. SN2' attack with retention of configuration is the predominant pathway. For example, reaction of oxabicycloheptene I with Me3CLi and CuCN in THF gave butylcyclohexenol II in 85% yield. [on SciFinder(R)]|
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