Synthesis of alpha-amino-acids by addition of ...
|Title||Synthesis of alpha-amino-acids by addition of putative azido radicals to alpha-methoxy acrylonitriles derived from aldehydes and ketones|
|Author(s)||D. L. J. Clive, Nola Etkin|
|Abstract||alpha-Methoxy acrylonitriles, available from aldehydes and ketones, react with sodium azide in the presence of eerie ammonium nitrate to give azido nitrates; from these compounds, alpha-amino acids are obtained by sequential treatment with sodium acetate in acetic acid and then methanolic potassium carbonate, followed by hydrogenation.|
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