Reactivity of fluorenylideneketene towards amines. A ...



Title Reactivity of fluorenylideneketene towards amines. A laser photolysis study with ultraviolet and infrared detection.
Author(s) N. C. deLucas, J. C. NettoFerreira, J. Andraos, J. Lusztyk, Brian D. Wagner, J. C. Scaiano
Journal Tetrahedron Letters
Date 1997
Volume 38
Issue 29
Start page 5147
End page 5150
Abstract The ketene derived from diazoquinone 5 can be readily detected by laser photolysis techniques with IR detection and its behavior agrees with that observed with more conventional UV-visible detection. The ketene reacts with amines (e.g. k similar to 7 x 10(7) M-1 s(-1) for diethylamine) to give ylides (yielding amides as final products) that absorb in the 300-340 nm and 1670-1680 cm(-1) regions. (C) 1997 Elsevier Science Ltd.

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