Reactivity of fluorenylideneketene towards amines. A ...
|Title||Reactivity of fluorenylideneketene towards amines. A laser photolysis study with ultraviolet and infrared detection.|
|Author(s)||N. C. deLucas, J. C. NettoFerreira, J. Andraos, J. Lusztyk, Brian D. Wagner, J. C. Scaiano|
|Abstract||The ketene derived from diazoquinone 5 can be readily detected by laser photolysis techniques with IR detection and its behavior agrees with that observed with more conventional UV-visible detection. The ketene reacts with amines (e.g. k similar to 7 x 10(7) M-1 s(-1) for diethylamine) to give ylides (yielding amides as final products) that absorb in the 300-340 nm and 1670-1680 cm(-1) regions. (C) 1997 Elsevier Science Ltd.|
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