The effect of solvent viscosity on the population ...
|Title||The effect of solvent viscosity on the population relaxation times of the S1 state of azulene and related compounds|
|Author(s)||D. Tittelbachhelmrich, Brian D. Wagner, R. P. Steer|
|Journal||Chemical Physics Letters|
|Abstract||The S1 population decay times of azulene and 4,6,8-trimethylazulene have been measured in solvents with a wide range of viscosities using a two-photon, two-color, pump-probe method. The S, lifetimes vary as expected on the basis of the energy gap law. No effect of solvent viscosity is observed, contrary to a previous suggestion. Data for 2-chloroazulene in non-viscous solvents are also reported.|
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