The effect of solvent viscosity on the population ...



Title The effect of solvent viscosity on the population relaxation times of the S1 state of azulene and related compounds
Author(s) D. Tittelbachhelmrich, Brian D. Wagner, R. P. Steer
Journal Chemical Physics Letters
Date 1993
Volume 209
Issue 5-6
Start page 464
End page 468
Abstract The S1 population decay times of azulene and 4,6,8-trimethylazulene have been measured in solvents with a wide range of viscosities using a two-photon, two-color, pump-probe method. The S, lifetimes vary as expected on the basis of the energy gap law. No effect of solvent viscosity is observed, contrary to a previous suggestion. Data for 2-chloroazulene in non-viscous solvents are also reported.

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