Sulfur ylides generated from the reaction of ...

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Title Sulfur ylides generated from the reaction of adamantylidene and phenylcarbene with sulfur substrates
Author(s) Y. N. Romashin, Michael T. H. Liu, B. T. Hill, M. S. Platz
Journal Tetrahedron Letters
Date 2003
Volume 44
Issue 34
Start page 6519
End page 6521
Abstract Reaction of adamantylidene and phenylcarbene with ethylthiol, ethylene dithiol, allylethylsulfide, allylphenylsulfide, and trimethylenesulfide involves the formation of a sulfur ylide intermediate, followed by H-migration, 2,3-sigmatropic shift, or ring opening to give sulfides. The sulfur ylide formed in the reaction of phenylcarbene with trimethylenesulfide is directly observed by laser flash photolytic techniques. (C) 2003 Elsevier Ltd. All rights reserved.

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