A nonspectroscopic method to determine the ...
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| Title | A nonspectroscopic method to determine the photolytic decomposition pathways of 3-chloro-3-alkyldiazirine: Carbene, diazo and rearrangement in excited state |
| Author(s) | T. Wakahara, Y. Niino, T. Kato, Y. Maeda, T. Akasaka, M. Liu, K. Kobayashi, S. Nagase |
| Journal | Journal of the American Chemical Society |
| Date | 2002 |
| Volume | 124 |
| Issue | 32 |
| Start page | 9465 |
| End page | 9468 |
| Abstract | C-60 acts as a mechanistic probe for the formation of carbene, diazo compound, and for the rearranged product via the excited state in the photolysis of 3-chloro-3-isopropyldiazirine and 3-chloro-3-chloromethyldiazirine. The carbene adds to C-60 to form methanofullerene, whereas the diazo compound adds to C-60 to form fulleroid. The olefin product arises as a result of the rearrangement in the excited state. |
| ISSN | 0002-7863 |
Using APA 6th Edition citation style.
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