Sulfur ylides generated from the reaction of ...



Title Sulfur ylides generated from the reaction of arylchlorocarbenes with trimethylenesulide: determination of rate parameters by laser flash photolysis
Author(s) Y. N. Romashin, Michael T. H. Liu, R. Bonneau
Journal Tetrahedron Letters
Date 2001
Volume 42
Issue 2
Start page 207
End page 209
Abstract Reaction of arylchlorodiazirines with trimethylenesulfide gives a mixture of aryldi(3-chloropropyl)thioacetal and aryl(2-propenyl)(3-chloropropyl)thioacetal in a good yield. The reaction goes through a formation of a sulfur ylide as an intermediate. Rate constants have been determined using laser flash photolytic techniques. (C) 2000 Elsevier Science Ltd. All rights reserved.

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