Self quenching reaction of (Phenoxymethyl) ...
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Citation
| Title | Self quenching reaction of (Phenoxymethyl) chlorocarbene with diazirine |
| Author(s) | M. Liu, J. Chateauneuf |
| Journal | Research on Chemical Intermediates |
| Date | 1994 |
| Volume | 20 |
| Issue | 2 |
| Start page | 195 |
| End page | 199 |
| Abstract | The combination of laser flash photolysis and product analysis demonstrates that even though (phenoxymethyl)chlorocarbene reacts with its diazirine precursor with a substantial rate constant of 3.5 x 10(8) M(-1)s(-1), the predicted azine product is not formed. These results indicate either carbene/diazirine reversibility or subsequent hydrogen migration of the carbene/diazirine adduct. Also, a rate constant of 2.0 x 10(7) s(-1) for the 12-hydrogen atom migration in (p-nitrophenoxymethyl)chlorocarbene has been determined using the pyridinium ylide technique. |
| ISSN | 0922-6168 |
Using APA 6th Edition citation style.
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