Kinetics of intramolecular and intermolecular ...
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Citation
| Title | Kinetics of intramolecular and intermolecular reactions of benzylchlorocarbene |
| Author(s) | M. Liu, R. Chapman, R. Bonneau |
| Journal | Journal of Photochemistry and Photobiology A-Chemistry |
| Date | 1992 |
| Volume | 63 |
| Issue | 1 |
| Start page | 115 |
| End page | 118 |
| Abstract | Photolysis of 3-chloro-3-benzyldiazirine in tetramethylethylene gives E- and Z-beta-chlorostyrenes and cyclopropane. Relative rate studies show that the styrenes to cyclopropane ratio increases with increasing diazirine concentration. This permits the determination of the ratio k(D)/k(i) = 8 where k(D) is the rate constant for the reaction of carbene with diazirine and k(i) is the rate constant for the 1,2-hydrogen atom shift of carbene. Laser flash photolysis yields the first absolute rate constant for the reaction of a chlorocarbene with diazirine and a value of 7.7 for k(D)/k(i). |
| ISSN | 1010-6030 |
Using APA 6th Edition citation style.
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