Structure, solvatochromism, and solvation of ...
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| Title | Structure, solvatochromism, and solvation of trans-[Co-III(cyclam)(NCS)(2)](NCS) and the structure of [Co-II(Me(4)cyclam)(NCS)](2)[Co(NCS)(4)]MeOH |
| Author(s) | J. Burgess, J. Fawcett, R. Haines, K. Singh, D. Russell |
| Journal | Transition Metal Chemistry |
| Date | 1999 |
| Volume | 24 |
| Issue | 3 |
| Start page | 355 |
| End page | 361 |
| Abstract | The structures of trans-[Co-III(cyclam)(NCS)(2)](NCS) and of [Co-II(Me(4)cyclam)(NCS)](2)[Co(NCS)(4)]. MeOH have been established by X-ray diffraction methods. The solvatochromic behavior of the trans-[Co(cyclam)(NCS)(2)](+) cation in several binary aqueous solvent mixtures is reported. Transfer chemical potentials for this complex from H2O into MeOH-H2O mixtures have been established from solubility measurements on its thiocyanate salt. The solvatochromic behavior of this cation is discussed in the context of other solvatochromic inorganic complexes; its transfer chemical potentials are discussed in relation to those of other cobalt(III) complexes. |
| ISSN | 0340-4285 |
Using APA 6th Edition citation style.
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