Kinetics and mechanisms of formation and of ...



Title Kinetics and mechanisms of formation and of reactions of intermediates in the Iron(II)-Phenanthroline-Cyanide and related sequences of compounds
Author(s) J. Burgess, Robert I. Haines
Journal Journal of the Chemical Society. Dalton Transactions
Date 1978
Issue 11
Start page 1447
End page 1451
Abstract Rate laws and rate constants are reported for the two stages of the reactions of [Fe(L?L)2(CN)2](L?L = 1,10-phenanthroline, 5-chloro-1,10-phenanthroline, or 2,2-bipyridyl) with cyanide ion in aqueous solution. The preparation of [Fe(5NO2-phen?CN)2(5NO2-phen)], an intermediate in the reaction of [Fe(5NO2-phen)3]2+ with cyanide to give [Fe(5NO2-phen)2(CN)2], is described, and the kinetics and mechanisms of some of its reactions, especially with hydroxide and with cyanide, are reported and discussed.
DOI 10.1039/DT9780001447
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