Kinetics of ring opening of substituted ...



Title Kinetics of ring opening of substituted cyclobutenediones by platinum(0) complexes
Author(s) J. Burgess, Robert I. Haines, E. R. Hamner, R. W. D. Kemmitt, M. A. R. Smith
Journal Journal of the Chemical Society, Dalton Transactions
Date 1975
Issue 23
Start page 2579
End page 2582
Abstract Kinetic data are reported for ring opening of benzocyclobutene-1,2-dione, 3-phenylcyclobutene-1,2-dione, 4-methoxy-3-phenylcyclobutene-1,2-dione, and 3,4-dimethoxycyclobutene-1,2-dione with the zerovalent platinum complexes [Pt(trans-PhCHCHPh)(PPh3)2] and [Pt(PhCCPh)(PPh3)2]. Possible mechanisms, intramolecular in chloroform and dissociative in benzene, are proposed in the light of these results
DOI 10.1039/DT9750002579
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