Outer-sphere electron transfer reactions of ...
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| Title | Outer-sphere electron transfer reactions of aqua(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-1-acetato) nickel(II) and (III) |
| Author(s) | R. Haines, D. Hutchings |
| Journal | Canadian Journal of Chemistry |
| Date | 2003 |
| Volume | 81 |
| Issue | 2 |
| Start page | 186 |
| Abstract | Features a study that examined the kinetics of oxidation of the nickel (II) tetraazamacrocyclic complex, 5,5,7,12,12,14-hexa-methyl-1,4,8,11-tetraazacyclotetradecane-1-acetate, which bears one pendant acetato group to the nickel (III) state. Discussion on the use of the resulting nickel (III) macrocycle as a potential inner-sphere oxidant in relation to its reaction with hexaaquairon (II); Electron paramagnetic resonance spectroscopy and electrochemistry; Results and discussion.; Features a study that examined the kinetics of oxidation of the nickel (II) tetraazamacrocyclic complex, 5,5,7,12,12,14-hexa-methyl-1,4,8,11-tetraazacyclotetradecane-1-acetate, which bears one pendant acetato group to the nickel (III) state. Discussion on the use of the resulting nickel (III) macrocycle as a potential inner-sphere oxidant in relation to its reaction with hexaaquairon (II); Electron paramagnetic resonance spectroscopy and electrochemistry; Results and discussion. |
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