Michael T. H. Liu

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NameMichael T. H. Liu
PositionEmeritus Faculty
Emailliu@upei.ca
Department(s)Chemistry
Website

Research Interests

  • Carbenes
  • 1,2-Hydrogen Migration
  • laser flash photolysis
  • azomethine ylide
  • 1,5-cylization, synthesis of biologically active nitrogen-containing heterocycles
  • C60 carbene adducts

Other Scholars in Chemistry

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TitleAuthor(s)
Kinetics and mechanism of the thermal decomposition of N-nitrosodiphenylmethylimineLiu, Michael T. H.; Ibata, T.
A nonspectroscopic method to determine the photolytic decomposition pathways of 3-chloro-3-alkyldiazirineWakahara, T.; Niino, Y.; Kato, T.; Maeda, Y.; Akasaka, T.; Liu, Michael T. H.; Kobayashi, K.; Nagase, S.
Kinetics and mechanism of unimolecular decomposition of 3-methyl-1para-tolyltriazeneVaughan, K.; Liu, Michael T. H.
Photolysis of m-phenylene-bis(Chlorodiazirine)+2-vinylpyridineBonneau, R.; Collado, D.; Liu, Michael T. H.
New synthesis of 2,2 '-heteroarylpyrroles from heteroarylchlorocarbenesRomashin, Y. N.; Liu, Michael T. H.; Ma, W.; Moss, R. A.
MNDO calculations on diazirinesBurkholder, D.; Jones, W. E.; Ling, K. W.; Wasson, J. S.; Liu, Michael T. H.
Rates for 1, 2-migration in alkylchlorocarbenesBonneau, R.; Liu, Michael T. H.; Rayez, M. T.
Deformation density studies of ring systems. 2. The deformation density of the diazirine ring in the X-ray structure of 3-[(p-Nitrophenoxy) methyl]-3-chlorodiazirineKwiatkowski, W.; Bakshi, P. K.; Cameron, T. S.; Liu, Michael T. H.
Synthesis of 3-chloro-3-methyl-d3-diazirineLiu, Michael T. H.; Chishti, N. H.; Burkholder, C. D.; Jones, W. E.; Wasson, J. S.
Benzylchlorocarbene : kinetics parameters for 1,2-H migration, UB absorption spectrum, and mechanism for addition to alkenesLiu, Michael T. H.; Bonneau, R.
Reactive intermediates in the photolysis and thermolysis of 3-chloro-3-benzyldiazirineLiu, Michael T. H.; Chishti, N. H.; Tencer, M.; Tomioka, H.; Izawa, Y.
S-heterocyclic carbene with a disilane backboneNikawa, H.; Nakahodo, T.; Tsuchiya, T.; Wakahara, T.; Rahman, G. M. A.; Akasaka, T.; Maeda, Y.; Liu, Michael T. H.; Meguro, A.; Kyushin, S.; Matsumoto, H.; Mizorogi, N.; Nagase, S.
1,2-Hydrogen migration in carbenes and mimicking processesBonneau, R.; Liu, Michael T. H.
Electrochemical behavior of diazirinesElson, C. M.; Liu, Michael T. H.
Pyridine ylide formation by capture of phenylchlorocarbene and tert-butylchlorocarbene. Reaction rates of an alkylchlorocarbene by laser flash photolysisJackson, J. E.; Soundararajan, N.; Platz, M. S.; Liu, Michael T. H.
Thermolysis and photolysis of 3-chloro-3-benzyldiazirines in alkenes; evidence for a carbene-alkene complexLiu, Michael T. H.; Soundararajan, N.; Paike, N.; Subramanian, R.
Spectroscopy and dynamics of para-nitrophenylchlorocarbeneBonneau, R.; Liu, Michael T. H.
Carbonyl ylide from 3-chloro-3-p-nitrophenylcarbene and acetoneIbata, T.; Liu, Michael T. H.; Toyoda, J.
Mass spectrometric identification of polycycloaddition of arylchlorocarbenes and fluorenylidene to buckministerfullereneLiu, Michael T. H.; Romashin, Y. N.; Kubota, M.; Ohashi, M.
Does Gd@C82 have an anomalous endohedral structure? Synthesis and ingle Crystal x-ray structure of the carbene adductAkasaka, Takeshi; Kono, Takayoshi; Takematsu, Yuji; Nikawa, Hidefumi; Nakahodo, Tsukasa; Wakahara, Takatsugu; Ishitsuka, Midori O.; Tsuchiya, Takahiro; Maeda, Yutaka; Liu, Michael T. H.; Yoza, Kenji; Kato, Tatsuhisa; Yamamoto, Kazunori; Mizorogi, Naomi; Slanina, Zdenek; Nagase, Shigeru
Photolysis and thermolysis of 3-normal-butyl-3-phenyldiazirineLiu, Michael T. H.; Palmer, G. E.; Chishti, N. H.
Sulfur ylides generated from the reaction of adamantylidene and phenylcarbene with sulfur substratesRomashin, Y. N.; Liu, Michael T. H.; Hill, B. T.; Platz, M. S.
Hydrogen bonding in alcohols: its effect on the carbene insertion reactionGriller, D.; Liu, Michael T. H.; Scaiano, J. C.
Spectroscopic detection of ammonium ylides from arylchlorocarbenes and aminesBonneau, R.; Liu, Michael T. H.
Detection of carbonyl oxide from singlet para-nitrophenylchlorocarbene and oxygenLiu, Michael T. H.; Bonneau, R.; Jefford, C. W.
Benzylbromocarbene: absolute rate constant for 1,2-hydrogen migration and ambiphilicityBonneau, R.; Liu, Michael T. H.; Suresh, R. V.
The thermal decomposition of diazirines: 3-(3-methyldiazirin-3-yl)propan-1-ol and 3-(3-methyldiazirin-3-yl)propanoic acidStevens, I. D. R.; Liu, Michael T. H.; Soundararajan, N.; Paike, N.
Reaction of benzylchlorocarbene with hydrogen chlorideLiu, Michael T. H.; Subramanian, R.
Photolysis of 3-chlorodiazirine in the presence of alkenes. Kinetic evidence for intervention of a carbene-alkene intermediate in addition of chlorocarbene to alkeneTomioka, H.; Hayashi, N.; Izawa, Y.; Liu, Michael T. H.
Benzylchlorocarbene: a new ambiphileLiu, Michael T. H.; Suresh, R. V.; Soundararajan, N.; Vessey, E. G.
Deformation density of A diazirene ring in the X-ray structure of 3-[(Para-nitrophenoxy)methyl]-3-chorodiazirine Cameron, T. S.; Bakshi, P. K.; Borecka, B.; Liu, Michael T. H.
Formation of a dipolar adduct in the reaction of arylchlorocarbenes with diethyl maleateDoyle, M. P.; Loh, K. L.; Nishioka, L. I.; Mcvickar, M. B.; Liu, Michael T. H.
Metal atoms collinear with the spiro carbon of 6,6-open adducts, M2@C80(Ad) (M = La and Ce, Ad = adamantylidene)Yamada, M.; Someya, C.; Wakahara, T.; Tsuchiya, T.; Maeda, Y.; Akasaka, T.; Yoza, K.; Horn, E.; Liu, Michael T. H.; Mizorogi, N.; Nagase, S.
Photolysis fo 3-chlorodiazirine in the presence of alkenes: orientational factors in the intermolecular interception of chlorocarbene by alkenesTomioka, H.; Hayashi, N.; Izawa, Y.; Liu, Michael T. H.
Activation energy for a 1, 2-hydrogen shift in (phenoxymethyl) chlorocarbeneChateauneuf, J. E.; Liu, Michael T. H.
Energy barrier for 1,2-hydrogen migration in benzylbromocarbeneLiu, Michael T. H.; Subramanian, R.
Photolysis of diazirines in the presence of C-60Akasaka, T.; Liu, Michael T. H.; Niino, Y.; Maeda, Y.; Wakahara, T.; Okamura, M.; Kobayashi, K.; Nagase, S.
Self quenching reaction of (Phenoxymethyl) chlorocarbene with diazirineLiu, Michael T. H.; Chateauneuf, J. E.
Temperature and matrix effects on competitive intermolecular and intramolecular reaction of benzylchlorocarbenes in ethanolTomioka, H.; Hayashi, N.; Izawa, Y.; Liu, Michael T. H.
Facile formation of azines from reactions of singlet methylene and dimethylcarbene with precursor diazirinesShustov, G. V.; Liu, Michael T. H.; Houk, K. N.
Excitation and dissociation of 3-chloro-3-methyldiazirine and 1-pyrazoline by low-energy electron impactLiu, Michael T. H.; Tanaka, T.; Hirotsu, T.; Fukui, K.; Fujita, I.; Kuwata, K.
Equilibrium constants for triphenylmethyl bromide and 3-bromo-3-phenyldiazirine in acetonitrileLiu, Michael T. H.; Paike, N.
1, 2-H shift in benzylchlorocarbene Liu, Michael T. H.; Bonneau, R.; Wierlacher, S.; Sander, W.
BenzylchlorocarbeneMerrer, D. C.; Moss, R. A.; Liu, Michael T. H.; Banks, J. T.; Ingold, K. U.
A verification of the photolytic decomposition pathways of 3-tert-butyl-3-chlorodiazirine based on the application of the C-60 probe techniqueIshitsuka, M. O.; Niino, Y.; Wakahara, T.; Akasaka, T.; Liu, Michael T. H.; Kobayashi, K.; Nagase, S.
Substituent and temperature effects on the reactions of benzylchlorocarbene with alcoholLiu, Michael T. H.; Subramanian, R.
Energy barrier for 1,2-hydrogen migration in benzylchlorocarbeneLiu, Michael T. H.
Thermolysis and photolysis of arylchlorodiazirines in allyl bromideBonneau, R.; Grobys, M.; Liu, Michael T. H.; Himori, M.; Fukushima, K.; Ibata, T.
Study of 1, 2-chlorine migration in (Alpha,alpha-dichlorobenzyl) chlorocarbene generated by laser flash photolysis of 3-chloro-3-(Alpha,alpha-dichlorobenzyl) diazirineLiu, Michael T. H.; Bonneau, R.
Spectroscopic, kinetic, and structural properties of rotamers of the 2-vinylpyridinium ylide of phenylchlorocarbeneBonneau, R.; Collado, D.; Dalibart, M.; Liu, Michael T. H.
Structural determination of metallofuIlerene SC3C82 revisitedLiduka, Y.; Wakahara, T.; Nakahodo, T.; Tsuchiya, T.; Sakuraba, A.; Maeda, Y.; Akasaka, T.; Yoza, K.; Horn, E.; Kato, T.; Liu, Michael T. H.; Mizorogi, N.; Kobayashi, K.; Nagase, S.
Dihydrosilaanthracenylidene and dihydroanthracenylideneSekiguchi, A.; Ando, W.; Sugawara, T.; Iwamura, H.; Liu, Michael T. H.
Adamantylidene revisitedBonneau, R.; Hellrung, B.; Liu, Michael T. H.; Wirz, J.
Studies on benzylchlorocarbeneLiu, Michael T. H.; Suresh, R. V.
On the possibility of conversion of strained bridgehead alkenes into carbenes via 1,2 hydrogen and 1,2 carbon migrations. A theoretical study of the rearrangements in the adamantene and protoadamantene systemsShustov, G. V.; Liu, Michael T. H.
Catalysis of olefin isomerization by tight ion pairsLiu, Michael T. H.; Doyle, M. P.; Loh, K. L.; Anand, S. M.
Reaction of 3-chloro-3-methyldiazirines with hydrogen atomsBurkholder, C. D.; Jones, W. E.; Wasson, J. S.; Liu, Michael T. H.
Activation parameters for the reaction of phenylchloro carbene with pyridine, tri- n -butyltin hydride, and triethylsilane; evidence against the need to invoke reversibly formed complexes in the reaction of this carbene with olefinsJackson, J. E.; Soundararajan, N.; Platz, M. S.; Doyle, M. P.; Liu, Michael T. H.
Absolute rate constants for the reactions of some arylchlorocarbenes with acetic acidGriller, D.; Liu, Michael T. H.; Montgomery, C. R.; Scaiano, J. C.; Wong, P. C.
Formation of indolizines by the addition of α-chloroacrylonitrile to pyridinium ylides: regioselectivity and Hammett correlationBonneau, R.; Liu, Michael T. H.; Lapouvade, R.
Time-resolved-absorption spectroscopic detection of 10,10-dimethyl-10-silaanthracen-9(10H)-one oxideSugawara, T.; Iwamura, H.; Hayashi, H.; Sekiguchi, A.; Ando, W.; Liu, Michael T. H.
The order of CH3CHO decomposition - commentLiu, Michael T. H.
Addition of an electrophilic carbene to an electron-deficient olefin. Kinetics of benzylchlorocarbene-diethyl fumarate reactionLiu, Michael T. H.; Subramanian, R.
Sulfur ylides generated from the reaction of arylchlorocarbenes with trimethylenesulideRomashin, Y. N.; Liu, Michael T. H.; Bonneau, R.
A dipyridoimidazolium salt from phenylchlorocarbene and 2,2 '-bipyridylBonneau, R.; Liu, Michael T. H.
Arylchlorocarbenes in the synthesis of heterocycles containing two nitrogen atomsRomashin, Y. N.; Liu, Michael T. H.; Nijjar, S. S.; Attanasi, O. A.
Reaction of phenylchlorocarbene in oxygen-doped matricesGanzer, G. A.; Sheridan, R. S.; Liu, Michael T. H.
A laser flash photolysis study of carbonyl ylides of arylchlorocarbenes: kinetics and reversibility of the formation, cyclization, and cycloadditionBonneau, R.; Liu, Michael T. H.
Methylchlorocarbene: measurement of rate constants for 1,2-hydrogen migration and addition to alkenesLiu, Michael T. H.; Bonneau, R.
The facile synthesis of 1,2,3-trisubstituted pyrroles from the reaction of chlorocarbenes with 1-azabuta-1,3-dienesRomashin, Y. N.; Liu, Michael T. H.; Bonneau, R.
Chemical modification of endohedral metallofullerene La@C82 with 3-chloro-3-phenyldiazirineIshitsuka, Midori O.; Enoki, Haruka; Tsuchiya, Takahiro; Slanina, Zdenek; Mizorogi, Naomi; Nagase, Shigeru; Liu, Michael T. H.; Akasaka, Takeshi
Cycloaddition of arylchlorocarbenes using ultrasoundBertram, A. K.; Liu, Michael T. H.
Gas phase protonation of diazirinesMatsumoto, T.; Kobayashi, S.; Mishima, M.; Shustov, G. V.; Liu, Michael T. H.
Carboxylation of carbenes in low-temperature matrixesWierlacher, S.; Sander, W.; Liu, Michael T. H.
Kinetic studies of chloro-p-nitrophenylcarbene with acetone and diethyl fumarateLiu, Michael T. H.; Soundararajan, N.; Anand, S. M.; Ibata, T.
Rearrangement of alkylchlorocarbenesBonneau, R.; Liu, Michael T. H.; Kim, K. C.; Goodman, J. L.
Effect of diazirine concentration on the reaction of 3-benzyl-3-chlorodiazirine with methanolLiu, Michael T. H.; Subramanian, R.
Isolation and characterization of carbene derivatives of LaC82(Cs)Akasaka, Takeshi; Kono, Takayoshi; Matsunaga, Yoichiro; Wakahara, Takatsugu; Nakahodo, Tsukasa; Ishitsuka, Midori; Maeda, Yutaka; Tsuchiya, Takahiro; Kato, Tatsuhias; Liu, Michael T.H.; Mizorogi, Naomi; Slanina, Zdenek; Nagase, Shigeru
Laser Flash Photolysis Studies: 1, 2-Hydrogen Migration to a CarbeneLiu, Michael T. H.
Effect of substituents on the thermal decomposition of diazirinesLiu, Michael T. H.; Choe, Y. K.; Kimura, M.; Kobayashi, K.; Nagase, S.; Wakahara, T.; Niino, Y.; Ishitsuka, M. O.; Maeda, Y.; Akasaka, T.
Kinetics of intramolecular and intermolecular reactions of benzylchlorocarbeneLiu, Michael T. H.; Chapman, R. G.; Bonneau, R.
Determination of the photolytic decomposition pathways of benzylchlorodiazirine by C60 probe techniqueIshitsuka, M. O.; Enoki, H.; Nikawa, H.; Wakahara, T.; Tsuchiya, T.; Akasaka, T.; Liu, Michael T. H.
Laser flash photolysis study of substituent effects on the rate of 1, 2-H migration in a series of benzylchlorocarbenesLiu, Michael T. H.; Bonneau, R.
Rearrangement of an ammonium ylide: mechanisms and kinetic parametersBonneau, R.; Reuter, I.; Liu, Michael T. H.
Spectroscopic detection of an arylchlorocarbene-ethyl acetate carbonyl ylide and subsequent oxirane formationChateauneuf, J. E.; Liu, Michael T. H.
Laser flash photolysis studies of nitrogen ylides generated by the reaction of arylchlorocarbenes with substituted vinylpyridines and 1-azabuta-1,3-dienesBonneau, R.; Romashin, Y. N.; Liu, Michael T. H.
Pyrolysis of trifluoroacetaldehyde, initiated by di-tertiary-butyl peroxide decompositionLoucks, L. F.; Liu, Michael T. H.; Hooper, D. G.
Quantum yield of formation of diazo compounds from the photolysis of diazirinesBonneau, R.; Liu, Michael T. H.
Nanorods of endohedral metallofullerene derivativeTsuchiya, Takahiro; Kumashiro, Ryotaro; Tanigaki, Katsumi; Matsunaga, Yoichiro; Ishitsuka, Midori O.; Wakahara, Takatsugu; Maeda, Yutaka; Takano, Yuta; Aoyagi, Motoki; Akasaka, Takeshi; Liu, Michael T. H.; Kato, Tatsuhisa; Suenaga, Kazutomo; Jeong, Jong S.; Iijima, Sumio; Kimura, Fumiko; Kimura, Tsunehisa; Nagasev, Shigeru
Photolysis of alkylhalodiazirines and direct observation of benzylchlorocarbene in cryogenic matrixesWierlacher, S.; Sander, W.; Liu, Michael T. H.
The thermolysis and photolysis of diazirines Liu, Michael T. H.
Reactivity and selectivity in intermolecular insertion reactions of chlorophenylcarbeneDoyle, M. P.; Taunton, J.; Oon, S. M.; Liu, Michael T. H.; Soundararajan, N.; Platz, M. S.; Jackson, J. E.
First determination of an absolute rate constant for a 1, 2‐phenyl migration to a carbeneLiu, Michael T. H.
Transformation of phenylchlorodiazirines to 1,3-dioxolanes and a 1,3-dithiolaneLiu, Michael T. H.; Kokosi, J.
Time-resolved and low-temperature absorption spectroscopic studies on 10-silaanthracen-9(10H)-ylideneSugawara, T.; Iwamura, H.; Hayashi, H.; Sekiguchi, A.; Ando, W.; Liu, Michael T. H.
Thermal decomposition of diazirines in the presence of meta-chloroperoxybenzoic acid. A method to determine the partitioning of reaction pathwaysLiu, Michael T. H.; Yamamoto, I.
on the thermal decomposition of diazirinesLiu, Michael T. H.; Tencer, M.; Stevens, I. D. R.
Electronic effect on 1,2-hydrogen shift in chlorocarbenesLiu, Michael T. H.; Tencer, M.
Preparation and crystal structure of 3-(1-naphthylmethyl)-3-chlorodiazirineLinden, A.; Cameron, T. S.; Liu, Michael T. H.; Anand, S. M.
Energy barrier for 1,2-chlorine migration in α-methyl-αlpha-chlorobenzyl(chloro)carbeneLiu, Michael T. H.; Murray, S.; Zhu, J. H.
Addition of arylchlorocarbenes to .alpha.,.beta.-unsaturated esters. Absolute rates, substituent effects, and variable reactivitiesSoundararajan, N.; Platz, M. S.; Jackson, J. E.; Doyle, M. P.; Oon, S. M.; Liu, Michael T. H.; Anand, S. M.
Insertion of phenylchlorocarbenes in the C-H bonds of alkanes: measurement of the rate constants by laser flash photolysisBonneau, R.; Liu, Michael T. H.
Behavior of carbonyl ylide generated from 3-chloro-3-(p-nitrophenyl)diazirine and acetone 1,3-dipolar cycloaddition to benzaldehyde and epoxide formationIbata, T.; Toyoda, J.; Liu, Michael T. H.
Experimental and theoretical studies of the scandium carbide endohedral metallofullerene Sc2C2@C-82 and its carbene derivativeIiduka, Y.; Wakahara, T.; Nakajima, K.; Nakahodo, T.; Tsuchiya, T.; Maeda, Y.; Akasaka, T.; Yoza, K.; Liu, Michael T. H.; Mizorogi, N.; Nagase, S.
Energy barrier for cyclopropylchlorocarbene rearrangement measured by direct observation of the carbene in laser flash spectroscopyLiu, Michael T. H.; Bonneau, R.
Photolysis of 3-chloro-3-aryldiazirines in the presence of amines and allyl alcoholLiu, Michael T. H.; Romashin, Y. N.; Venkatachalam, T. K.
Measurement of the absolute rate of 1,2-hydrogen migration in benzylchlorocarbeneJackson, J. E.; Soundararajan, N.; White, W.; Liu, Michael T. H.; Bonneau, R.; Platz, M. S.
The barrier for 1, 2-hydrogen shift in dialkyl carbenesStevens, I. D. R.; Liu, Michael T. H.; Soundararajan, N.; Paike, N.
Termolecular trapping of benzylchlorocarbene by methanolLiu, Michael T. H.; Subramanian, R.
Kinetic and spectroscopic properties of carbene-diazirine ylidesBonneau, R.; Liu, Michael T. H.
Laser flash photolysis studies on intra- and intermolecular reactions of some halocarbenesLiu, Michael T. H.; Bonneau, R.
Synthesis of 3-substituted indolizines from the reaction of chlorocarbenes with 2-vinylpyridineBonneau, R.; Romashin, Y. N.; Liu, Michael T. H.; Macpherson, S. E.
Photochemical decomposition of pyrazoline produced in the reaction of C60 with DiazoadamantaneNiino, Y.; Wakahara, T.; Akasaka, T.; Liu, Michael T. H.
Origin of the stereoselectivity of the intramolecular 1,2-hydrogen shift in singlet chlorocarbenes. A theoretical studyShustov, G. V.; Liu, Michael T. H.; Rauk, A.
A study of the vacuum pyrolysis of para-substituted diazoacetophenones with He(I) ultraviolet photoelectron spectroscopyWerstiuk, N. H.; Muchall, H. M.; Ma, J. G.; Liu, Michael T. H.
Photo-labelling of C60 with 3-trifluoro-3-phenyldiazirineLiu, Michael T. H.
Isolation and characterization of a carbene derivative of La@C-82Maeda, Y.; Matsunaga, Y.; Wakahara, T.; Takahashi, S.; Tsuchiya, T.; Ishitsuka, M. O.; Hasegawa, T.; Akasaka, T.; Liu, Michael T. H.; Kokura, K.; Horn, E.; Yoza, K.; Kato, T.; Okubo, S.; Kobayashi, K.; Nagase, S.; Yamamoto, K.
Direct measurement of the energy barrier for 1,2-chlorine atom migration in α-methyl-α-chlorobenzyl (Chloro) crbeneLiu, Michael T. H.; Chateauneuf, J. E.
Electron spin resonance studies of diazirine anion radicalsElson, C. M.; Liu, Michael T. H.; Mailer, C.
Kinetics of the oxidation of cyclohexene by thallium(II1) acetateLoucks, L. F.; Liu, Michael T. H.; Durant, D. K.
Kinetics of the 1, 5‐dipolar cyclization of 2‐Vinylpyridinium ylides to Indolizines. Determination of rate parameters by laser flash photolysisLiu, Michael T. H.; Romashin, Y. N.; Bonneau, R.
Absolute rate constant for the reaction of benzylchlorocarbene with hydrogen chlorideLiu, Michael T. H.; Chateauneuf, J. E.
Benzylchlorocarbene: UV absorption spectrum, kinetics for 1,2-H migration and mechanism for reaction with acetic acid as determined by combined continuous and laser-flash photolysisBonneau, R.; Liu, Michael T. H.; Subramanian, R.; Linkletter, Barry A.; Stevens, I. D. R.

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Kinetics and mechanism of the thermal decomposition of N-nitrosodiphenylmethylimine - ir:ir-batch6-146831520:19:37 2015-08-23
A nonspectroscopic method to determine the photolytic decomposition pathways of 3-chloro-3-alkyldiazirine - ir:ir-batch6-137234019:07:03 2015-08-24
Kinetics and mechanism of unimolecular decomposition of 3-methyl-1para-tolyltriazene - ir:ir-batch6-146736120:19:45 2015-08-23
Photolysis of m-phenylene-bis(Chlorodiazirine)+2-vinylpyridine - ir:ir-batch6-136934220:19:48 2015-08-23
New synthesis of 2,2 '-heteroarylpyrroles from heteroarylchlorocarbenes - ir:ir-batch6-137831700:55:25 2015-08-26
MNDO calculations on diazirines - ir:ir-batch6-147234720:20:03 2015-08-23
Rates for 1, 2-migration in alkylchlorocarbenes - ir:ir-batch6-142133821:34:08 2015-08-25
Deformation density studies of ring systems. 2. The deformation density of the diazirine ring in the X-ray structure of 3-[(p-Nitrophenoxy) methyl]-3-chlorodiazirine - ir:ir-batch6-139532220:20:30 2015-08-23
Synthesis of 3-chloro-3-methyl-d3-diazirine - ir:ir-batch6-147132008:30:26 2015-08-27
Benzylchlorocarbene : kinetics parameters for 1,2-H migration, UB absorption spectrum, and mechanism for addition to alkenes - ir:ir-batch6-141832820:20:43 2015-08-23
Reactive intermediates in the photolysis and thermolysis of 3-chloro-3-benzyldiazirine - ir:ir-batch6-145731512:31:39 2015-08-27
S-heterocyclic carbene with a disilane backbone - ir:ir-batch6-136333216:02:21 2015-08-26
1,2-Hydrogen migration in carbenes and mimicking processes - ir:ir-batch6-148634903:00:21 2015-08-27
Electrochemical behavior of diazirines - ir:ir-batch6-146637610:05:15 2015-08-25
Pyridine ylide formation by capture of phenylchlorocarbene and tert-butylchlorocarbene. Reaction rates of an alkylchlorocarbene by laser flash photolysis - ir:ir-batch6-143332701:47:12 2015-08-27
Thermolysis and photolysis of 3-chloro-3-benzyldiazirines in alkenes; evidence for a carbene-alkene complex - ir:ir-batch6-143731503:36:18 2015-08-27
Spectroscopy and dynamics of para-nitrophenylchlorocarbene - ir:ir-batch6-142633202:49:16 2015-08-28
Carbonyl ylide from 3-chloro-3-p-nitrophenylcarbene and acetone - ir:ir-batch6-144132312:07:07 2015-08-23
Mass spectrometric identification of polycycloaddition of arylchlorocarbenes and fluorenylidene to buckministerfullerene - ir:ir-batch6-139430712:08:07 2015-08-23
Does Gd@C82 have an anomalous endohedral structure? Synthesis and ingle Crystal x-ray structure of the carbene adduct - ir:ir-batch6-603136318:16:48 2015-08-26
Photolysis and thermolysis of 3-normal-butyl-3-phenyldiazirine - ir:ir-batch6-146930012:02:47 2015-08-23
Sulfur ylides generated from the reaction of adamantylidene and phenylcarbene with sulfur substrates - ir:ir-batch6-137137617:22:46 2015-08-24
Hydrogen bonding in alcohols: its effect on the carbene insertion reaction - ir:ir-batch6-146328518:22:38 2015-08-24
Spectroscopic detection of ammonium ylides from arylchlorocarbenes and amines - ir:ir-batch6-141031419:31:52 2015-08-23
Detection of carbonyl oxide from singlet para-nitrophenylchlorocarbene and oxygen - ir:ir-batch6-141530907:32:23 2015-08-25
Benzylbromocarbene: absolute rate constant for 1,2-hydrogen migration and ambiphilicity - ir:ir-batch6-142530712:40:21 2015-08-25
The thermal decomposition of diazirines: 3-(3-methyldiazirin-3-yl)propan-1-ol and 3-(3-methyldiazirin-3-yl)propanoic acid - ir:ir-batch6-141733915:05:38 2015-08-27
Reaction of benzylchlorocarbene with hydrogen chloride - ir:ir-batch6-144931923:35:17 2015-08-27
Photolysis of 3-chlorodiazirine in the presence of alkenes. Kinetic evidence for intervention of a carbene-alkene intermediate in addition of chlorocarbene to alkene - ir:ir-batch6-145833212:23:21 2015-08-23
Benzylchlorocarbene: a new ambiphile - ir:ir-batch6-142930518:37:42 2015-08-27
Deformation density of A diazirene ring in the X-ray structure of 3-[(Para-nitrophenoxy)methyl]-3-chorodiazirine - ir:ir-batch6-140740523:48:36 2015-08-27
Formation of a dipolar adduct in the reaction of arylchlorocarbenes with diethyl maleate - ir:ir-batch6-144232421:49:20 2015-08-27
Metal atoms collinear with the spiro carbon of 6,6-open adducts, M2@C80(Ad) (M = La and Ce, Ad = adamantylidene) - ir:ir-batch6-603233100:23:59 2015-08-26
Photolysis fo 3-chlorodiazirine in the presence of alkenes: orientational factors in the intermolecular interception of chlorocarbene by alkenes - ir:ir-batch6-145629209:34:43 2015-08-24
Activation energy for a 1, 2-hydrogen shift in (phenoxymethyl) chlorocarbene - ir:ir-batch6-141232622:39:52 2015-08-24
Energy barrier for 1,2-hydrogen migration in benzylbromocarbene - ir:ir-batch6-144733122:09:59 2015-08-27
Photolysis of diazirines in the presence of C-60 - ir:ir-batch6-137431019:12:23 2015-08-24
Self quenching reaction of (Phenoxymethyl) chlorocarbene with diazirine - ir:ir-batch6-139730016:58:48 2015-08-26
Temperature and matrix effects on competitive intermolecular and intramolecular reaction of benzylchlorocarbenes in ethanol - ir:ir-batch6-145434002:05:04 2015-08-26
Facile formation of azines from reactions of singlet methylene and dimethylcarbene with precursor diazirines - ir:ir-batch6-137929209:58:45 2015-08-26
Excitation and dissociation of 3-chloro-3-methyldiazirine and 1-pyrazoline by low-energy electron impact - ir:ir-batch6-147031112:22:04 2015-08-27
Equilibrium constants for triphenylmethyl bromide and 3-bromo-3-phenyldiazirine in acetonitrile - ir:ir-batch6-143835106:29:54 2015-08-26
1, 2-H shift in benzylchlorocarbene - ir:ir-batch6-139031422:39:49 2015-08-27
Benzylchlorocarbene - ir:ir-batch6-138533200:41:38 2015-08-27
A verification of the photolytic decomposition pathways of 3-tert-butyl-3-chlorodiazirine based on the application of the C-60 probe technique - ir:ir-batch6-136634322:05:19 2015-08-27
Substituent and temperature effects on the reactions of benzylchlorocarbene with alcohol - ir:ir-batch6-144329613:10:19 2015-08-26
Energy barrier for 1,2-hydrogen migration in benzylchlorocarbene - ir:ir-batch6-145027921:32:20 2015-08-27
Thermolysis and photolysis of arylchlorodiazirines in allyl bromide - ir:ir-batch6-139635709:46:25 2015-08-26
Study of 1, 2-chlorine migration in (Alpha,alpha-dichlorobenzyl) chlorocarbene generated by laser flash photolysis of 3-chloro-3-(Alpha,alpha-dichlorobenzyl) diazirine - ir:ir-batch6-140631620:30:24 2015-08-27
Spectroscopic, kinetic, and structural properties of rotamers of the 2-vinylpyridinium ylide of phenylchlorocarbene - ir:ir-batch6-136828312:06:07 2015-08-23
Structural determination of metallofuIlerene SC3C82 revisited - ir:ir-batch6-136432810:17:08 2015-08-23
Dihydrosilaanthracenylidene and dihydroanthracenylidene - ir:ir-batch6-146529922:36:18 2015-08-26
Adamantylidene revisited - ir:ir-batch6-138432010:02:28 2015-08-27
Studies on benzylchlorocarbene - ir:ir-batch6-143031016:19:53 2015-08-26
On the possibility of conversion of strained bridgehead alkenes into carbenes via 1,2 hydrogen and 1,2 carbon migrations. A theoretical study of the rearrangements in the adamantene and protoadamantene systems - ir:ir-batch6-138230323:14:02 2015-08-27
Catalysis of olefin isomerization by tight ion pairs - ir:ir-batch6-144027700:48:18 2015-08-24
Reaction of 3-chloro-3-methyldiazirines with hydrogen atoms - ir:ir-batch6-147326922:57:20 2015-08-20
Activation parameters for the reaction of phenylchloro carbene with pyridine, tri- n -butyltin hydride, and triethylsilane; evidence against the need to invoke reversibly formed complexes in the reaction of this carbene with olefins - ir:ir-batch6-142729202:38:15 2015-08-28
Absolute rate constants for the reactions of some arylchlorocarbenes with acetic acid - ir:ir-batch6-146233923:13:33 2015-08-27
Formation of indolizines by the addition of α-chloroacrylonitrile to pyridinium ylides: regioselectivity and Hammett correlation - ir:ir-batch6-142430812:47:51 2015-08-27
Time-resolved-absorption spectroscopic detection of 10,10-dimethyl-10-silaanthracen-9(10H)-one oxide - ir:ir-batch6-146128907:36:18 2015-08-27
The order of CH3CHO decomposition - comment - ir:ir-batch6-145333607:43:19 2015-08-27
Addition of an electrophilic carbene to an electron-deficient olefin. Kinetics of benzylchlorocarbene-diethyl fumarate reaction - ir:ir-batch6-145230623:57:42 2015-08-27
Sulfur ylides generated from the reaction of arylchlorocarbenes with trimethylenesulide - ir:ir-batch6-137327309:26:24 2015-08-26
A dipyridoimidazolium salt from phenylchlorocarbene and 2,2 '-bipyridyl - ir:ir-batch6-136530323:34:40 2015-08-26
Arylchlorocarbenes in the synthesis of heterocycles containing two nitrogen atoms - ir:ir-batch6-137532301:44:08 2015-08-28
Reaction of phenylchlorocarbene in oxygen-doped matrices - ir:ir-batch6-144530816:45:47 2015-08-27
A laser flash photolysis study of carbonyl ylides of arylchlorocarbenes: kinetics and reversibility of the formation, cyclization, and cycloaddition - ir:ir-batch6-141928602:33:10 2015-08-28
Methylchlorocarbene: measurement of rate constants for 1,2-hydrogen migration and addition to alkenes - ir:ir-batch6-142232315:53:12 2015-08-27
The facile synthesis of 1,2,3-trisubstituted pyrroles from the reaction of chlorocarbenes with 1-azabuta-1,3-dienes - ir:ir-batch6-138033802:21:10 2015-08-28
Chemical modification of endohedral metallofullerene La@C82 with 3-chloro-3-phenyldiazirine - ir:30939006:47:34 2015-08-27
Cycloaddition of arylchlorocarbenes using ultrasound - ir:ir-batch6-140229816:33:30 2015-08-26
Gas phase protonation of diazirines - ir:ir-batch6-138328223:43:32 2015-08-27
Carboxylation of carbenes in low-temperature matrixes - ir:ir-batch6-140931916:10:13 2015-08-26
Kinetic studies of chloro-p-nitrophenylcarbene with acetone and diethyl fumarate - ir:ir-batch6-143932305:29:52 2015-08-26
Rearrangement of alkylchlorocarbenes - ir:ir-batch6-138929703:20:36 2015-08-27
Effect of diazirine concentration on the reaction of 3-benzyl-3-chlorodiazirine with methanol - ir:ir-batch6-143528008:46:50 2015-08-27
Isolation and characterization of carbene derivatives of LaC82(Cs) - ir:66141301:39:15 2015-08-28
Laser Flash Photolysis Studies: 1, 2-Hydrogen Migration to a Carbene - ir:ir-batch6-139233612:03:47 2015-08-23
Effect of substituents on the thermal decomposition of diazirines - ir:ir-batch6-137029017:25:55 2015-08-24
Kinetics of intramolecular and intermolecular reactions of benzylchlorocarbene - ir:ir-batch6-140831714:48:43 2015-08-26
Determination of the photolytic decomposition pathways of benzylchlorodiazirine by C60 probe technique - ir:ir-batch6-136230204:58:23 2015-08-25
Laser flash photolysis study of substituent effects on the rate of 1, 2-H migration in a series of benzylchlorocarbenes - ir:ir-batch6-140530103:26:33 2015-08-27
Rearrangement of an ammonium ylide: mechanisms and kinetic parameters - ir:ir-batch6-139828917:41:48 2015-08-27
Spectroscopic detection of an arylchlorocarbene-ethyl acetate carbonyl ylide and subsequent oxirane formation - ir:ir-batch6-141334811:38:11 2015-08-25
Laser flash photolysis studies of nitrogen ylides generated by the reaction of arylchlorocarbenes with substituted vinylpyridines and 1-azabuta-1,3-dienes - ir:ir-batch6-137734020:31:24 2015-08-27
Pyrolysis of trifluoroacetaldehyde, initiated by di-tertiary-butyl peroxide decomposition - ir:ir-batch6-147428001:06:33 2015-08-28
Quantum yield of formation of diazo compounds from the photolysis of diazirines - ir:ir-batch6-138832910:31:11 2015-08-27
Nanorods of endohedral metallofullerene derivative - ir:66238610:18:52 2015-08-27
Photolysis of alkylhalodiazirines and direct observation of benzylchlorocarbene in cryogenic matrixes - ir:ir-batch6-140130121:54:40 2015-08-27
The thermolysis and photolysis of diazirines - ir:ir-batch6-146426811:23:23 2015-08-25
Reactivity and selectivity in intermolecular insertion reactions of chlorophenylcarbene - ir:ir-batch6-143131501:28:55 2015-08-26
First determination of an absolute rate constant for a 1, 2‐phenyl migration to a carbene - ir:ir-batch6-140031722:08:04 2015-08-27
Transformation of phenylchlorodiazirines to 1,3-dioxolanes and a 1,3-dithiolane - ir:ir-batch6-144829319:16:37 2015-08-27
Time-resolved and low-temperature absorption spectroscopic studies on 10-silaanthracen-9(10H)-ylidene - ir:ir-batch6-146028415:38:09 2015-08-26
Thermal decomposition of diazirines in the presence of meta-chloroperoxybenzoic acid. A method to determine the partitioning of reaction pathways - ir:ir-batch6-147530319:26:35 2015-08-25
on the thermal decomposition of diazirines - ir:ir-batch6-144630719:15:45 2015-08-27
Electronic effect on 1,2-hydrogen shift in chlorocarbenes - ir:ir-batch6-145928805:56:05 2015-08-26
Preparation and crystal structure of 3-(1-naphthylmethyl)-3-chlorodiazirine - ir:ir-batch6-143427115:52:45 2015-08-23
Energy barrier for 1,2-chlorine migration in α-methyl-αlpha-chlorobenzyl(chloro)carbene - ir:ir-batch6-141430017:25:38 2015-08-27
Addition of arylchlorocarbenes to .alpha.,.beta.-unsaturated esters. Absolute rates, substituent effects, and variable reactivities - ir:ir-batch6-143234511:22:50 2015-08-25
Insertion of phenylchlorocarbenes in the C-H bonds of alkanes: measurement of the rate constants by laser flash photolysis - ir:ir-batch6-140329618:21:34 2015-08-27
Behavior of carbonyl ylide generated from 3-chloro-3-(p-nitrophenyl)diazirine and acetone 1,3-dipolar cycloaddition to benzaldehyde and epoxide formation - ir:ir-batch6-143635321:17:42 2015-08-24
Experimental and theoretical studies of the scandium carbide endohedral metallofullerene Sc2C2@C-82 and its carbene derivative - ir:ir-batch6-554734512:09:17 2015-08-23
Energy barrier for cyclopropylchlorocarbene rearrangement measured by direct observation of the carbene in laser flash spectroscopy - ir:ir-batch6-142029918:39:56 2015-08-27
Photolysis of 3-chloro-3-aryldiazirines in the presence of amines and allyl alcohol - ir:ir-batch6-139330712:46:35 2015-08-26
Measurement of the absolute rate of 1,2-hydrogen migration in benzylchlorocarbene - ir:ir-batch6-142331607:23:41 2015-08-27
The barrier for 1, 2-hydrogen shift in dialkyl carbenes - ir:ir-batch6-142829619:12:59 2015-08-24
Termolecular trapping of benzylchlorocarbene by methanol - ir:ir-batch6-145529207:29:47 2015-08-26
Kinetic and spectroscopic properties of carbene-diazirine ylides - ir:ir-batch6-137630912:06:17 2015-08-23
Laser flash photolysis studies on intra- and intermolecular reactions of some halocarbenes - ir:ir-batch6-138727701:05:24 2015-08-25
Synthesis of 3-substituted indolizines from the reaction of chlorocarbenes with 2-vinylpyridine - ir:ir-batch6-139928606:37:11 2015-08-26
Photochemical decomposition of pyrazoline produced in the reaction of C60 with Diazoadamantane - ir:ir-batch6-148529500:01:24 2015-08-24
Origin of the stereoselectivity of the intramolecular 1,2-hydrogen shift in singlet chlorocarbenes. A theoretical study - ir:ir-batch6-138633206:06:15 2015-08-24
A study of the vacuum pyrolysis of para-substituted diazoacetophenones with He(I) ultraviolet photoelectron spectroscopy - ir:ir-batch6-138131210:05:22 2015-08-26
Photo-labelling of C60 with 3-trifluoro-3-phenyldiazirine - ir:ir-batch6-554629812:23:37 2015-08-23
Isolation and characterization of a carbene derivative of La@C-82 - ir:ir-batch6-136730703:16:57 2015-08-27
Direct measurement of the energy barrier for 1,2-chlorine atom migration in α-methyl-α-chlorobenzyl (Chloro) crbene - ir:ir-batch6-140430021:23:30 2015-08-27
Electron spin resonance studies of diazirine anion radicals - ir:ir-batch6-144429920:10:21 2015-08-27
Kinetics of the oxidation of cyclohexene by thallium(II1) acetate - ir:ir-batch6-145127323:17:12 2015-08-26
Kinetics of the 1, 5‐dipolar cyclization of 2‐Vinylpyridinium ylides to Indolizines. Determination of rate parameters by laser flash photolysis - ir:ir-batch6-139131512:00:11 2015-08-27
Absolute rate constant for the reaction of benzylchlorocarbene with hydrogen chloride - ir:ir-batch6-141134004:23:19 2015-08-25
Benzylchlorocarbene: UV absorption spectrum, kinetics for 1,2-H migration and mechanism for reaction with acetic acid as determined by combined continuous and laser-flash photolysis - ir:ir-batch6-141659019:54:27 2015-08-27