Michael T. H. Liu

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NameMichael T. H. Liu
PositionEmeritus Faculty
Emailliu@upei.ca
Department(s)Chemistry
Website

Research Interests

  • Carbenes
  • 1,2-Hydrogen Migration
  • laser flash photolysis
  • azomethine ylide
  • 1,5-cylization, synthesis of biologically active nitrogen-containing heterocycles
  • C60 carbene adducts

Other Scholars in Chemistry

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TitleAuthor(s)
Kinetics and mechanism of the thermal decomposition of N-nitrosodiphenylmethylimineLiu, Michael T. H.; Ibata, T.
A nonspectroscopic method to determine the photolytic decomposition pathways of 3-chloro-3-alkyldiazirineWakahara, T.; Niino, Y.; Kato, T.; Maeda, Y.; Akasaka, T.; Liu, Michael T. H.; Kobayashi, K.; Nagase, S.
Kinetics and mechanism of unimolecular decomposition of 3-methyl-1para-tolyltriazeneVaughan, K.; Liu, Michael T. H.
Photolysis of m-phenylene-bis(Chlorodiazirine)+2-vinylpyridineBonneau, R.; Collado, D.; Liu, Michael T. H.
New synthesis of 2,2 '-heteroarylpyrroles from heteroarylchlorocarbenesRomashin, Y. N.; Liu, Michael T. H.; Ma, W.; Moss, R. A.
MNDO calculations on diazirinesBurkholder, D.; Jones, W. E.; Ling, K. W.; Wasson, J. S.; Liu, Michael T. H.
Rates for 1, 2-migration in alkylchlorocarbenesBonneau, R.; Liu, Michael T. H.; Rayez, M. T.
Deformation density studies of ring systems. 2. The deformation density of the diazirine ring in the X-ray structure of 3-[(p-Nitrophenoxy) methyl]-3-chlorodiazirineKwiatkowski, W.; Bakshi, P. K.; Cameron, T. S.; Liu, Michael T. H.
Synthesis of 3-chloro-3-methyl-d3-diazirineLiu, Michael T. H.; Chishti, N. H.; Burkholder, C. D.; Jones, W. E.; Wasson, J. S.
Benzylchlorocarbene : kinetics parameters for 1,2-H migration, UB absorption spectrum, and mechanism for addition to alkenesLiu, Michael T. H.; Bonneau, R.
Reactive intermediates in the photolysis and thermolysis of 3-chloro-3-benzyldiazirineLiu, Michael T. H.; Chishti, N. H.; Tencer, M.; Tomioka, H.; Izawa, Y.
S-heterocyclic carbene with a disilane backboneNikawa, H.; Nakahodo, T.; Tsuchiya, T.; Wakahara, T.; Rahman, G. M. A.; Akasaka, T.; Maeda, Y.; Liu, Michael T. H.; Meguro, A.; Kyushin, S.; Matsumoto, H.; Mizorogi, N.; Nagase, S.
1,2-Hydrogen migration in carbenes and mimicking processesBonneau, R.; Liu, Michael T. H.
Electrochemical behavior of diazirinesElson, C. M.; Liu, Michael T. H.
Pyridine ylide formation by capture of phenylchlorocarbene and tert-butylchlorocarbene. Reaction rates of an alkylchlorocarbene by laser flash photolysisJackson, J. E.; Soundararajan, N.; Platz, M. S.; Liu, Michael T. H.
Thermolysis and photolysis of 3-chloro-3-benzyldiazirines in alkenes; evidence for a carbene-alkene complexLiu, Michael T. H.; Soundararajan, N.; Paike, N.; Subramanian, R.
Spectroscopy and dynamics of para-nitrophenylchlorocarbeneBonneau, R.; Liu, Michael T. H.
Carbonyl ylide from 3-chloro-3-p-nitrophenylcarbene and acetoneIbata, T.; Liu, Michael T. H.; Toyoda, J.
Mass spectrometric identification of polycycloaddition of arylchlorocarbenes and fluorenylidene to buckministerfullereneLiu, Michael T. H.; Romashin, Y. N.; Kubota, M.; Ohashi, M.
Does Gd@C82 have an anomalous endohedral structure? Synthesis and ingle Crystal x-ray structure of the carbene adductAkasaka, Takeshi; Kono, Takayoshi; Takematsu, Yuji; Nikawa, Hidefumi; Nakahodo, Tsukasa; Wakahara, Takatsugu; Ishitsuka, Midori O.; Tsuchiya, Takahiro; Maeda, Yutaka; Liu, Michael T. H.; Yoza, Kenji; Kato, Tatsuhisa; Yamamoto, Kazunori; Mizorogi, Naomi; Slanina, Zdenek; Nagase, Shigeru
Photolysis and thermolysis of 3-normal-butyl-3-phenyldiazirineLiu, Michael T. H.; Palmer, G. E.; Chishti, N. H.
Sulfur ylides generated from the reaction of adamantylidene and phenylcarbene with sulfur substratesRomashin, Y. N.; Liu, Michael T. H.; Hill, B. T.; Platz, M. S.
Hydrogen bonding in alcohols: its effect on the carbene insertion reactionGriller, D.; Liu, Michael T. H.; Scaiano, J. C.
Spectroscopic detection of ammonium ylides from arylchlorocarbenes and aminesBonneau, R.; Liu, Michael T. H.
Detection of carbonyl oxide from singlet para-nitrophenylchlorocarbene and oxygenLiu, Michael T. H.; Bonneau, R.; Jefford, C. W.
Benzylbromocarbene: absolute rate constant for 1,2-hydrogen migration and ambiphilicityBonneau, R.; Liu, Michael T. H.; Suresh, R. V.
The thermal decomposition of diazirines: 3-(3-methyldiazirin-3-yl)propan-1-ol and 3-(3-methyldiazirin-3-yl)propanoic acidStevens, I. D. R.; Liu, Michael T. H.; Soundararajan, N.; Paike, N.
Reaction of benzylchlorocarbene with hydrogen chlorideLiu, Michael T. H.; Subramanian, R.
Photolysis of 3-chlorodiazirine in the presence of alkenes. Kinetic evidence for intervention of a carbene-alkene intermediate in addition of chlorocarbene to alkeneTomioka, H.; Hayashi, N.; Izawa, Y.; Liu, Michael T. H.
Benzylchlorocarbene: a new ambiphileLiu, Michael T. H.; Suresh, R. V.; Soundararajan, N.; Vessey, E. G.
Deformation density of A diazirene ring in the X-ray structure of 3-[(Para-nitrophenoxy)methyl]-3-chorodiazirine Cameron, T. S.; Bakshi, P. K.; Borecka, B.; Liu, Michael T. H.
Formation of a dipolar adduct in the reaction of arylchlorocarbenes with diethyl maleateDoyle, M. P.; Loh, K. L.; Nishioka, L. I.; Mcvickar, M. B.; Liu, Michael T. H.
Metal atoms collinear with the spiro carbon of 6,6-open adducts, M2@C80(Ad) (M = La and Ce, Ad = adamantylidene)Yamada, M.; Someya, C.; Wakahara, T.; Tsuchiya, T.; Maeda, Y.; Akasaka, T.; Yoza, K.; Horn, E.; Liu, Michael T. H.; Mizorogi, N.; Nagase, S.
Photolysis fo 3-chlorodiazirine in the presence of alkenes: orientational factors in the intermolecular interception of chlorocarbene by alkenesTomioka, H.; Hayashi, N.; Izawa, Y.; Liu, Michael T. H.
Activation energy for a 1, 2-hydrogen shift in (phenoxymethyl) chlorocarbeneChateauneuf, J. E.; Liu, Michael T. H.
Energy barrier for 1,2-hydrogen migration in benzylbromocarbeneLiu, Michael T. H.; Subramanian, R.
Photolysis of diazirines in the presence of C-60Akasaka, T.; Liu, Michael T. H.; Niino, Y.; Maeda, Y.; Wakahara, T.; Okamura, M.; Kobayashi, K.; Nagase, S.
Self quenching reaction of (Phenoxymethyl) chlorocarbene with diazirineLiu, Michael T. H.; Chateauneuf, J. E.
Temperature and matrix effects on competitive intermolecular and intramolecular reaction of benzylchlorocarbenes in ethanolTomioka, H.; Hayashi, N.; Izawa, Y.; Liu, Michael T. H.
Facile formation of azines from reactions of singlet methylene and dimethylcarbene with precursor diazirinesShustov, G. V.; Liu, Michael T. H.; Houk, K. N.
Excitation and dissociation of 3-chloro-3-methyldiazirine and 1-pyrazoline by low-energy electron impactLiu, Michael T. H.; Tanaka, T.; Hirotsu, T.; Fukui, K.; Fujita, I.; Kuwata, K.
Equilibrium constants for triphenylmethyl bromide and 3-bromo-3-phenyldiazirine in acetonitrileLiu, Michael T. H.; Paike, N.
1, 2-H shift in benzylchlorocarbene Liu, Michael T. H.; Bonneau, R.; Wierlacher, S.; Sander, W.
BenzylchlorocarbeneMerrer, D. C.; Moss, R. A.; Liu, Michael T. H.; Banks, J. T.; Ingold, K. U.
A verification of the photolytic decomposition pathways of 3-tert-butyl-3-chlorodiazirine based on the application of the C-60 probe techniqueIshitsuka, M. O.; Niino, Y.; Wakahara, T.; Akasaka, T.; Liu, Michael T. H.; Kobayashi, K.; Nagase, S.
Substituent and temperature effects on the reactions of benzylchlorocarbene with alcoholLiu, Michael T. H.; Subramanian, R.
Energy barrier for 1,2-hydrogen migration in benzylchlorocarbeneLiu, Michael T. H.
Thermolysis and photolysis of arylchlorodiazirines in allyl bromideBonneau, R.; Grobys, M.; Liu, Michael T. H.; Himori, M.; Fukushima, K.; Ibata, T.
Study of 1, 2-chlorine migration in (Alpha,alpha-dichlorobenzyl) chlorocarbene generated by laser flash photolysis of 3-chloro-3-(Alpha,alpha-dichlorobenzyl) diazirineLiu, Michael T. H.; Bonneau, R.
Spectroscopic, kinetic, and structural properties of rotamers of the 2-vinylpyridinium ylide of phenylchlorocarbeneBonneau, R.; Collado, D.; Dalibart, M.; Liu, Michael T. H.
Structural determination of metallofuIlerene SC3C82 revisitedLiduka, Y.; Wakahara, T.; Nakahodo, T.; Tsuchiya, T.; Sakuraba, A.; Maeda, Y.; Akasaka, T.; Yoza, K.; Horn, E.; Kato, T.; Liu, Michael T. H.; Mizorogi, N.; Kobayashi, K.; Nagase, S.
Dihydrosilaanthracenylidene and dihydroanthracenylideneSekiguchi, A.; Ando, W.; Sugawara, T.; Iwamura, H.; Liu, Michael T. H.
Adamantylidene revisitedBonneau, R.; Hellrung, B.; Liu, Michael T. H.; Wirz, J.
Studies on benzylchlorocarbeneLiu, Michael T. H.; Suresh, R. V.
On the possibility of conversion of strained bridgehead alkenes into carbenes via 1,2 hydrogen and 1,2 carbon migrations. A theoretical study of the rearrangements in the adamantene and protoadamantene systemsShustov, G. V.; Liu, Michael T. H.
Catalysis of olefin isomerization by tight ion pairsLiu, Michael T. H.; Doyle, M. P.; Loh, K. L.; Anand, S. M.
Reaction of 3-chloro-3-methyldiazirines with hydrogen atomsBurkholder, C. D.; Jones, W. E.; Wasson, J. S.; Liu, Michael T. H.
Activation parameters for the reaction of phenylchloro carbene with pyridine, tri- n -butyltin hydride, and triethylsilane; evidence against the need to invoke reversibly formed complexes in the reaction of this carbene with olefinsJackson, J. E.; Soundararajan, N.; Platz, M. S.; Doyle, M. P.; Liu, Michael T. H.
Absolute rate constants for the reactions of some arylchlorocarbenes with acetic acidGriller, D.; Liu, Michael T. H.; Montgomery, C. R.; Scaiano, J. C.; Wong, P. C.
Formation of indolizines by the addition of α-chloroacrylonitrile to pyridinium ylides: regioselectivity and Hammett correlationBonneau, R.; Liu, Michael T. H.; Lapouvade, R.
Time-resolved-absorption spectroscopic detection of 10,10-dimethyl-10-silaanthracen-9(10H)-one oxideSugawara, T.; Iwamura, H.; Hayashi, H.; Sekiguchi, A.; Ando, W.; Liu, Michael T. H.
The order of CH3CHO decomposition - commentLiu, Michael T. H.
Addition of an electrophilic carbene to an electron-deficient olefin. Kinetics of benzylchlorocarbene-diethyl fumarate reactionLiu, Michael T. H.; Subramanian, R.
Sulfur ylides generated from the reaction of arylchlorocarbenes with trimethylenesulideRomashin, Y. N.; Liu, Michael T. H.; Bonneau, R.
A dipyridoimidazolium salt from phenylchlorocarbene and 2,2 '-bipyridylBonneau, R.; Liu, Michael T. H.
Arylchlorocarbenes in the synthesis of heterocycles containing two nitrogen atomsRomashin, Y. N.; Liu, Michael T. H.; Nijjar, S. S.; Attanasi, O. A.
Reaction of phenylchlorocarbene in oxygen-doped matricesGanzer, G. A.; Sheridan, R. S.; Liu, Michael T. H.
A laser flash photolysis study of carbonyl ylides of arylchlorocarbenes: kinetics and reversibility of the formation, cyclization, and cycloadditionBonneau, R.; Liu, Michael T. H.
Methylchlorocarbene: measurement of rate constants for 1,2-hydrogen migration and addition to alkenesLiu, Michael T. H.; Bonneau, R.
The facile synthesis of 1,2,3-trisubstituted pyrroles from the reaction of chlorocarbenes with 1-azabuta-1,3-dienesRomashin, Y. N.; Liu, Michael T. H.; Bonneau, R.
Chemical modification of endohedral metallofullerene La@C82 with 3-chloro-3-phenyldiazirineIshitsuka, Midori O.; Enoki, Haruka; Tsuchiya, Takahiro; Slanina, Zdenek; Mizorogi, Naomi; Nagase, Shigeru; Liu, Michael T. H.; Akasaka, Takeshi
Cycloaddition of arylchlorocarbenes using ultrasoundBertram, A. K.; Liu, Michael T. H.
Gas phase protonation of diazirinesMatsumoto, T.; Kobayashi, S.; Mishima, M.; Shustov, G. V.; Liu, Michael T. H.
Carboxylation of carbenes in low-temperature matrixesWierlacher, S.; Sander, W.; Liu, Michael T. H.
Kinetic studies of chloro-p-nitrophenylcarbene with acetone and diethyl fumarateLiu, Michael T. H.; Soundararajan, N.; Anand, S. M.; Ibata, T.
Rearrangement of alkylchlorocarbenesBonneau, R.; Liu, Michael T. H.; Kim, K. C.; Goodman, J. L.
Effect of diazirine concentration on the reaction of 3-benzyl-3-chlorodiazirine with methanolLiu, Michael T. H.; Subramanian, R.
Isolation and characterization of carbene derivatives of LaC82(Cs)Akasaka, Takeshi; Kono, Takayoshi; Matsunaga, Yoichiro; Wakahara, Takatsugu; Nakahodo, Tsukasa; Ishitsuka, Midori; Maeda, Yutaka; Tsuchiya, Takahiro; Kato, Tatsuhias; Liu, Michael T.H.; Mizorogi, Naomi; Slanina, Zdenek; Nagase, Shigeru
Laser Flash Photolysis Studies: 1, 2-Hydrogen Migration to a CarbeneLiu, Michael T. H.
Effect of substituents on the thermal decomposition of diazirinesLiu, Michael T. H.; Choe, Y. K.; Kimura, M.; Kobayashi, K.; Nagase, S.; Wakahara, T.; Niino, Y.; Ishitsuka, M. O.; Maeda, Y.; Akasaka, T.
Kinetics of intramolecular and intermolecular reactions of benzylchlorocarbeneLiu, Michael T. H.; Chapman, R. G.; Bonneau, R.
Determination of the photolytic decomposition pathways of benzylchlorodiazirine by C60 probe techniqueIshitsuka, M. O.; Enoki, H.; Nikawa, H.; Wakahara, T.; Tsuchiya, T.; Akasaka, T.; Liu, Michael T. H.
Laser flash photolysis study of substituent effects on the rate of 1, 2-H migration in a series of benzylchlorocarbenesLiu, Michael T. H.; Bonneau, R.
Rearrangement of an ammonium ylide: mechanisms and kinetic parametersBonneau, R.; Reuter, I.; Liu, Michael T. H.
Spectroscopic detection of an arylchlorocarbene-ethyl acetate carbonyl ylide and subsequent oxirane formationChateauneuf, J. E.; Liu, Michael T. H.
Laser flash photolysis studies of nitrogen ylides generated by the reaction of arylchlorocarbenes with substituted vinylpyridines and 1-azabuta-1,3-dienesBonneau, R.; Romashin, Y. N.; Liu, Michael T. H.
Pyrolysis of trifluoroacetaldehyde, initiated by di-tertiary-butyl peroxide decompositionLoucks, L. F.; Liu, Michael T. H.; Hooper, D. G.
Quantum yield of formation of diazo compounds from the photolysis of diazirinesBonneau, R.; Liu, Michael T. H.
Nanorods of endohedral metallofullerene derivativeTsuchiya, Takahiro; Kumashiro, Ryotaro; Tanigaki, Katsumi; Matsunaga, Yoichiro; Ishitsuka, Midori O.; Wakahara, Takatsugu; Maeda, Yutaka; Takano, Yuta; Aoyagi, Motoki; Akasaka, Takeshi; Liu, Michael T. H.; Kato, Tatsuhisa; Suenaga, Kazutomo; Jeong, Jong S.; Iijima, Sumio; Kimura, Fumiko; Kimura, Tsunehisa; Nagasev, Shigeru
Photolysis of alkylhalodiazirines and direct observation of benzylchlorocarbene in cryogenic matrixesWierlacher, S.; Sander, W.; Liu, Michael T. H.
The thermolysis and photolysis of diazirines Liu, Michael T. H.
Reactivity and selectivity in intermolecular insertion reactions of chlorophenylcarbeneDoyle, M. P.; Taunton, J.; Oon, S. M.; Liu, Michael T. H.; Soundararajan, N.; Platz, M. S.; Jackson, J. E.
First determination of an absolute rate constant for a 1, 2‐phenyl migration to a carbeneLiu, Michael T. H.
Transformation of phenylchlorodiazirines to 1,3-dioxolanes and a 1,3-dithiolaneLiu, Michael T. H.; Kokosi, J.
Time-resolved and low-temperature absorption spectroscopic studies on 10-silaanthracen-9(10H)-ylideneSugawara, T.; Iwamura, H.; Hayashi, H.; Sekiguchi, A.; Ando, W.; Liu, Michael T. H.
Thermal decomposition of diazirines in the presence of meta-chloroperoxybenzoic acid. A method to determine the partitioning of reaction pathwaysLiu, Michael T. H.; Yamamoto, I.
on the thermal decomposition of diazirinesLiu, Michael T. H.; Tencer, M.; Stevens, I. D. R.
Electronic effect on 1,2-hydrogen shift in chlorocarbenesLiu, Michael T. H.; Tencer, M.
Preparation and crystal structure of 3-(1-naphthylmethyl)-3-chlorodiazirineLinden, A.; Cameron, T. S.; Liu, Michael T. H.; Anand, S. M.
Energy barrier for 1,2-chlorine migration in α-methyl-αlpha-chlorobenzyl(chloro)carbeneLiu, Michael T. H.; Murray, S.; Zhu, J. H.
Addition of arylchlorocarbenes to .alpha.,.beta.-unsaturated esters. Absolute rates, substituent effects, and variable reactivitiesSoundararajan, N.; Platz, M. S.; Jackson, J. E.; Doyle, M. P.; Oon, S. M.; Liu, Michael T. H.; Anand, S. M.
Insertion of phenylchlorocarbenes in the C-H bonds of alkanes: measurement of the rate constants by laser flash photolysisBonneau, R.; Liu, Michael T. H.
Behavior of carbonyl ylide generated from 3-chloro-3-(p-nitrophenyl)diazirine and acetone 1,3-dipolar cycloaddition to benzaldehyde and epoxide formationIbata, T.; Toyoda, J.; Liu, Michael T. H.
Experimental and theoretical studies of the scandium carbide endohedral metallofullerene Sc2C2@C-82 and its carbene derivativeIiduka, Y.; Wakahara, T.; Nakajima, K.; Nakahodo, T.; Tsuchiya, T.; Maeda, Y.; Akasaka, T.; Yoza, K.; Liu, Michael T. H.; Mizorogi, N.; Nagase, S.
Energy barrier for cyclopropylchlorocarbene rearrangement measured by direct observation of the carbene in laser flash spectroscopyLiu, Michael T. H.; Bonneau, R.
Photolysis of 3-chloro-3-aryldiazirines in the presence of amines and allyl alcoholLiu, Michael T. H.; Romashin, Y. N.; Venkatachalam, T. K.
Measurement of the absolute rate of 1,2-hydrogen migration in benzylchlorocarbeneJackson, J. E.; Soundararajan, N.; White, W.; Liu, Michael T. H.; Bonneau, R.; Platz, M. S.
The barrier for 1, 2-hydrogen shift in dialkyl carbenesStevens, I. D. R.; Liu, Michael T. H.; Soundararajan, N.; Paike, N.
Termolecular trapping of benzylchlorocarbene by methanolLiu, Michael T. H.; Subramanian, R.
Kinetic and spectroscopic properties of carbene-diazirine ylidesBonneau, R.; Liu, Michael T. H.
Laser flash photolysis studies on intra- and intermolecular reactions of some halocarbenesLiu, Michael T. H.; Bonneau, R.
Synthesis of 3-substituted indolizines from the reaction of chlorocarbenes with 2-vinylpyridineBonneau, R.; Romashin, Y. N.; Liu, Michael T. H.; Macpherson, S. E.
Photochemical decomposition of pyrazoline produced in the reaction of C60 with DiazoadamantaneNiino, Y.; Wakahara, T.; Akasaka, T.; Liu, Michael T. H.
Origin of the stereoselectivity of the intramolecular 1,2-hydrogen shift in singlet chlorocarbenes. A theoretical studyShustov, G. V.; Liu, Michael T. H.; Rauk, A.
A study of the vacuum pyrolysis of para-substituted diazoacetophenones with He(I) ultraviolet photoelectron spectroscopyWerstiuk, N. H.; Muchall, H. M.; Ma, J. G.; Liu, Michael T. H.
Photo-labelling of C60 with 3-trifluoro-3-phenyldiazirineLiu, Michael T. H.
Isolation and characterization of a carbene derivative of La@C-82Maeda, Y.; Matsunaga, Y.; Wakahara, T.; Takahashi, S.; Tsuchiya, T.; Ishitsuka, M. O.; Hasegawa, T.; Akasaka, T.; Liu, Michael T. H.; Kokura, K.; Horn, E.; Yoza, K.; Kato, T.; Okubo, S.; Kobayashi, K.; Nagase, S.; Yamamoto, K.
Direct measurement of the energy barrier for 1,2-chlorine atom migration in α-methyl-α-chlorobenzyl (Chloro) crbeneLiu, Michael T. H.; Chateauneuf, J. E.
Electron spin resonance studies of diazirine anion radicalsElson, C. M.; Liu, Michael T. H.; Mailer, C.
Kinetics of the oxidation of cyclohexene by thallium(II1) acetateLoucks, L. F.; Liu, Michael T. H.; Durant, D. K.
Kinetics of the 1, 5‐dipolar cyclization of 2‐Vinylpyridinium ylides to Indolizines. Determination of rate parameters by laser flash photolysisLiu, Michael T. H.; Romashin, Y. N.; Bonneau, R.
Absolute rate constant for the reaction of benzylchlorocarbene with hydrogen chlorideLiu, Michael T. H.; Chateauneuf, J. E.
Benzylchlorocarbene: UV absorption spectrum, kinetics for 1,2-H migration and mechanism for reaction with acetic acid as determined by combined continuous and laser-flash photolysisBonneau, R.; Liu, Michael T. H.; Subramanian, R.; Linkletter, Barry A.; Stevens, I. D. R.

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Kinetics and mechanism of the thermal decomposition of N-nitrosodiphenylmethylimine - ir:ir-batch6-146829404:54:25 2015-07-03
A nonspectroscopic method to determine the photolytic decomposition pathways of 3-chloro-3-alkyldiazirine - ir:ir-batch6-137231806:37:11 2015-07-05
Kinetics and mechanism of unimolecular decomposition of 3-methyl-1para-tolyltriazene - ir:ir-batch6-146734321:58:08 2015-07-03
Photolysis of m-phenylene-bis(Chlorodiazirine)+2-vinylpyridine - ir:ir-batch6-136932309:24:56 2015-07-05
New synthesis of 2,2 '-heteroarylpyrroles from heteroarylchlorocarbenes - ir:ir-batch6-137830001:30:34 2015-07-03
MNDO calculations on diazirines - ir:ir-batch6-147232804:55:08 2015-07-03
Rates for 1, 2-migration in alkylchlorocarbenes - ir:ir-batch6-142131505:09:27 2015-07-04
Deformation density studies of ring systems. 2. The deformation density of the diazirine ring in the X-ray structure of 3-[(p-Nitrophenoxy) methyl]-3-chlorodiazirine - ir:ir-batch6-139530404:44:38 2015-07-04
Synthesis of 3-chloro-3-methyl-d3-diazirine - ir:ir-batch6-147129904:54:57 2015-07-03
Benzylchlorocarbene : kinetics parameters for 1,2-H migration, UB absorption spectrum, and mechanism for addition to alkenes - ir:ir-batch6-141831000:44:11 2015-07-04
Reactive intermediates in the photolysis and thermolysis of 3-chloro-3-benzyldiazirine - ir:ir-batch6-145729922:30:07 2015-07-04
S-heterocyclic carbene with a disilane backbone - ir:ir-batch6-136331009:20:47 2015-07-05
1,2-Hydrogen migration in carbenes and mimicking processes - ir:ir-batch6-148633310:20:54 2015-07-05
Electrochemical behavior of diazirines - ir:ir-batch6-146634820:04:09 2015-07-03
Pyridine ylide formation by capture of phenylchlorocarbene and tert-butylchlorocarbene. Reaction rates of an alkylchlorocarbene by laser flash photolysis - ir:ir-batch6-143330509:03:13 2015-07-05
Thermolysis and photolysis of 3-chloro-3-benzyldiazirines in alkenes; evidence for a carbene-alkene complex - ir:ir-batch6-143729707:08:26 2015-07-05
Spectroscopy and dynamics of para-nitrophenylchlorocarbene - ir:ir-batch6-142631317:43:57 2015-07-03
Carbonyl ylide from 3-chloro-3-p-nitrophenylcarbene and acetone - ir:ir-batch6-144130013:59:22 2015-06-30
Mass spectrometric identification of polycycloaddition of arylchlorocarbenes and fluorenylidene to buckministerfullerene - ir:ir-batch6-139428901:31:43 2015-07-05
Does Gd@C82 have an anomalous endohedral structure? Synthesis and ingle Crystal x-ray structure of the carbene adduct - ir:ir-batch6-603134007:24:09 2015-07-05
Photolysis and thermolysis of 3-normal-butyl-3-phenyldiazirine - ir:ir-batch6-146928421:53:43 2015-07-04
Sulfur ylides generated from the reaction of adamantylidene and phenylcarbene with sulfur substrates - ir:ir-batch6-137135307:36:11 2015-07-04
Hydrogen bonding in alcohols: its effect on the carbene insertion reaction - ir:ir-batch6-146326704:53:41 2015-07-03
Spectroscopic detection of ammonium ylides from arylchlorocarbenes and amines - ir:ir-batch6-141029321:31:31 2015-07-04
Detection of carbonyl oxide from singlet para-nitrophenylchlorocarbene and oxygen - ir:ir-batch6-141528814:58:53 2015-07-04
Benzylbromocarbene: absolute rate constant for 1,2-hydrogen migration and ambiphilicity - ir:ir-batch6-142529221:14:20 2015-07-04
The thermal decomposition of diazirines: 3-(3-methyldiazirin-3-yl)propan-1-ol and 3-(3-methyldiazirin-3-yl)propanoic acid - ir:ir-batch6-141731912:34:22 2015-07-02
Reaction of benzylchlorocarbene with hydrogen chloride - ir:ir-batch6-144929906:36:29 2015-07-05
Photolysis of 3-chlorodiazirine in the presence of alkenes. Kinetic evidence for intervention of a carbene-alkene intermediate in addition of chlorocarbene to alkene - ir:ir-batch6-145831314:17:37 2015-07-04
Benzylchlorocarbene: a new ambiphile - ir:ir-batch6-142928903:10:06 2015-07-05
Deformation density of A diazirene ring in the X-ray structure of 3-[(Para-nitrophenoxy)methyl]-3-chorodiazirine - ir:ir-batch6-140738710:51:23 2015-07-05
Formation of a dipolar adduct in the reaction of arylchlorocarbenes with diethyl maleate - ir:ir-batch6-144230904:16:28 2015-07-05
Metal atoms collinear with the spiro carbon of 6,6-open adducts, M2@C80(Ad) (M = La and Ce, Ad = adamantylidene) - ir:ir-batch6-603231008:56:19 2015-07-05
Photolysis fo 3-chlorodiazirine in the presence of alkenes: orientational factors in the intermolecular interception of chlorocarbene by alkenes - ir:ir-batch6-145627212:11:17 2015-07-05
Activation energy for a 1, 2-hydrogen shift in (phenoxymethyl) chlorocarbene - ir:ir-batch6-141230911:49:06 2015-07-05
Energy barrier for 1,2-hydrogen migration in benzylbromocarbene - ir:ir-batch6-144731410:41:12 2015-07-05
Photolysis of diazirines in the presence of C-60 - ir:ir-batch6-137429311:11:23 2015-07-04
Self quenching reaction of (Phenoxymethyl) chlorocarbene with diazirine - ir:ir-batch6-139728406:55:07 2015-07-05
Temperature and matrix effects on competitive intermolecular and intramolecular reaction of benzylchlorocarbenes in ethanol - ir:ir-batch6-145432206:46:11 2015-07-04
Facile formation of azines from reactions of singlet methylene and dimethylcarbene with precursor diazirines - ir:ir-batch6-137927314:12:18 2015-06-30
Excitation and dissociation of 3-chloro-3-methyldiazirine and 1-pyrazoline by low-energy electron impact - ir:ir-batch6-147029604:58:22 2015-07-05
Equilibrium constants for triphenylmethyl bromide and 3-bromo-3-phenyldiazirine in acetonitrile - ir:ir-batch6-143832909:36:42 2015-07-04
1, 2-H shift in benzylchlorocarbene - ir:ir-batch6-139029705:44:43 2015-07-05
Benzylchlorocarbene - ir:ir-batch6-138531022:47:16 2015-07-03
A verification of the photolytic decomposition pathways of 3-tert-butyl-3-chlorodiazirine based on the application of the C-60 probe technique - ir:ir-batch6-136632209:40:13 2015-07-04
Substituent and temperature effects on the reactions of benzylchlorocarbene with alcohol - ir:ir-batch6-144328012:29:03 2015-07-04
Energy barrier for 1,2-hydrogen migration in benzylchlorocarbene - ir:ir-batch6-145026112:16:58 2015-07-04
Thermolysis and photolysis of arylchlorodiazirines in allyl bromide - ir:ir-batch6-139633920:51:26 2015-07-03
Study of 1, 2-chlorine migration in (Alpha,alpha-dichlorobenzyl) chlorocarbene generated by laser flash photolysis of 3-chloro-3-(Alpha,alpha-dichlorobenzyl) diazirine - ir:ir-batch6-140630009:05:26 2015-07-05
Spectroscopic, kinetic, and structural properties of rotamers of the 2-vinylpyridinium ylide of phenylchlorocarbene - ir:ir-batch6-136826910:57:34 2015-07-05
Structural determination of metallofuIlerene SC3C82 revisited - ir:ir-batch6-136431202:21:47 2015-07-04
Dihydrosilaanthracenylidene and dihydroanthracenylidene - ir:ir-batch6-146528208:59:55 2015-07-05
Adamantylidene revisited - ir:ir-batch6-138430108:50:20 2015-07-05
Studies on benzylchlorocarbene - ir:ir-batch6-143029209:41:41 2015-07-04
On the possibility of conversion of strained bridgehead alkenes into carbenes via 1,2 hydrogen and 1,2 carbon migrations. A theoretical study of the rearrangements in the adamantene and protoadamantene systems - ir:ir-batch6-138228714:21:21 2015-07-04
Catalysis of olefin isomerization by tight ion pairs - ir:ir-batch6-144025111:10:40 2015-07-05
Reaction of 3-chloro-3-methyldiazirines with hydrogen atoms - ir:ir-batch6-147325401:10:56 2015-07-04
Activation parameters for the reaction of phenylchloro carbene with pyridine, tri- n -butyltin hydride, and triethylsilane; evidence against the need to invoke reversibly formed complexes in the reaction of this carbene with olefins - ir:ir-batch6-142727815:58:01 2015-07-04
Absolute rate constants for the reactions of some arylchlorocarbenes with acetic acid - ir:ir-batch6-146232105:49:08 2015-07-05
Formation of indolizines by the addition of α-chloroacrylonitrile to pyridinium ylides: regioselectivity and Hammett correlation - ir:ir-batch6-142429002:15:31 2015-07-05
Time-resolved-absorption spectroscopic detection of 10,10-dimethyl-10-silaanthracen-9(10H)-one oxide - ir:ir-batch6-146127402:24:32 2015-07-04
The order of CH3CHO decomposition - comment - ir:ir-batch6-145331607:42:15 2015-07-04
Addition of an electrophilic carbene to an electron-deficient olefin. Kinetics of benzylchlorocarbene-diethyl fumarate reaction - ir:ir-batch6-145228706:43:41 2015-07-05
Sulfur ylides generated from the reaction of arylchlorocarbenes with trimethylenesulide - ir:ir-batch6-137325404:16:27 2015-07-01
A dipyridoimidazolium salt from phenylchlorocarbene and 2,2 '-bipyridyl - ir:ir-batch6-136528814:02:38 2015-07-04
Arylchlorocarbenes in the synthesis of heterocycles containing two nitrogen atoms - ir:ir-batch6-137530501:33:46 2015-07-01
Reaction of phenylchlorocarbene in oxygen-doped matrices - ir:ir-batch6-144529304:04:15 2015-07-05
A laser flash photolysis study of carbonyl ylides of arylchlorocarbenes: kinetics and reversibility of the formation, cyclization, and cycloaddition - ir:ir-batch6-141926920:22:21 2015-07-03
Methylchlorocarbene: measurement of rate constants for 1,2-hydrogen migration and addition to alkenes - ir:ir-batch6-142230515:05:13 2015-07-03
The facile synthesis of 1,2,3-trisubstituted pyrroles from the reaction of chlorocarbenes with 1-azabuta-1,3-dienes - ir:ir-batch6-138032100:56:29 2015-07-03
Chemical modification of endohedral metallofullerene La@C82 with 3-chloro-3-phenyldiazirine - ir:30937016:17:46 2015-07-04
Cycloaddition of arylchlorocarbenes using ultrasound - ir:ir-batch6-140227806:27:05 2015-07-05
Gas phase protonation of diazirines - ir:ir-batch6-138326723:16:16 2015-07-03
Carboxylation of carbenes in low-temperature matrixes - ir:ir-batch6-140930017:34:40 2015-07-03
Kinetic studies of chloro-p-nitrophenylcarbene with acetone and diethyl fumarate - ir:ir-batch6-143931020:46:27 2015-07-04
Rearrangement of alkylchlorocarbenes - ir:ir-batch6-138927905:10:15 2015-07-04
Effect of diazirine concentration on the reaction of 3-benzyl-3-chlorodiazirine with methanol - ir:ir-batch6-143526011:27:16 2015-07-05
Isolation and characterization of carbene derivatives of LaC82(Cs) - ir:66138608:51:34 2015-07-05
Laser Flash Photolysis Studies: 1, 2-Hydrogen Migration to a Carbene - ir:ir-batch6-139231423:42:41 2015-07-03
Effect of substituents on the thermal decomposition of diazirines - ir:ir-batch6-137027008:24:17 2015-07-02
Kinetics of intramolecular and intermolecular reactions of benzylchlorocarbene - ir:ir-batch6-140829705:21:54 2015-07-05
Determination of the photolytic decomposition pathways of benzylchlorodiazirine by C60 probe technique - ir:ir-batch6-136228500:44:53 2015-07-04
Laser flash photolysis study of substituent effects on the rate of 1, 2-H migration in a series of benzylchlorocarbenes - ir:ir-batch6-140528419:35:16 2015-07-04
Rearrangement of an ammonium ylide: mechanisms and kinetic parameters - ir:ir-batch6-139827108:59:03 2015-07-03
Spectroscopic detection of an arylchlorocarbene-ethyl acetate carbonyl ylide and subsequent oxirane formation - ir:ir-batch6-141333308:13:58 2015-07-05
Laser flash photolysis studies of nitrogen ylides generated by the reaction of arylchlorocarbenes with substituted vinylpyridines and 1-azabuta-1,3-dienes - ir:ir-batch6-137732204:55:45 2015-07-04
Pyrolysis of trifluoroacetaldehyde, initiated by di-tertiary-butyl peroxide decomposition - ir:ir-batch6-147426700:08:26 2015-07-05
Quantum yield of formation of diazo compounds from the photolysis of diazirines - ir:ir-batch6-138830807:31:56 2015-07-04
Nanorods of endohedral metallofullerene derivative - ir:66236301:12:26 2015-07-05
Photolysis of alkylhalodiazirines and direct observation of benzylchlorocarbene in cryogenic matrixes - ir:ir-batch6-140128802:08:05 2015-07-05
The thermolysis and photolysis of diazirines - ir:ir-batch6-146424707:00:48 2015-07-05
Reactivity and selectivity in intermolecular insertion reactions of chlorophenylcarbene - ir:ir-batch6-143130210:52:47 2015-07-05
First determination of an absolute rate constant for a 1, 2‐phenyl migration to a carbene - ir:ir-batch6-140030002:52:42 2015-07-05
Transformation of phenylchlorodiazirines to 1,3-dioxolanes and a 1,3-dithiolane - ir:ir-batch6-144827814:22:09 2015-07-04
Time-resolved and low-temperature absorption spectroscopic studies on 10-silaanthracen-9(10H)-ylidene - ir:ir-batch6-146027104:35:20 2015-07-03
Thermal decomposition of diazirines in the presence of meta-chloroperoxybenzoic acid. A method to determine the partitioning of reaction pathways - ir:ir-batch6-147528704:02:03 2015-07-04
on the thermal decomposition of diazirines - ir:ir-batch6-144628917:37:51 2015-07-04
Electronic effect on 1,2-hydrogen shift in chlorocarbenes - ir:ir-batch6-145927300:21:02 2015-07-04
Preparation and crystal structure of 3-(1-naphthylmethyl)-3-chlorodiazirine - ir:ir-batch6-143425712:52:14 2015-07-03
Energy barrier for 1,2-chlorine migration in α-methyl-αlpha-chlorobenzyl(chloro)carbene - ir:ir-batch6-141428402:31:25 2015-07-05
Addition of arylchlorocarbenes to .alpha.,.beta.-unsaturated esters. Absolute rates, substituent effects, and variable reactivities - ir:ir-batch6-143232522:42:33 2015-07-03
Insertion of phenylchlorocarbenes in the C-H bonds of alkanes: measurement of the rate constants by laser flash photolysis - ir:ir-batch6-140327608:06:31 2015-07-05
Behavior of carbonyl ylide generated from 3-chloro-3-(p-nitrophenyl)diazirine and acetone 1,3-dipolar cycloaddition to benzaldehyde and epoxide formation - ir:ir-batch6-143634002:17:14 2015-07-05
Experimental and theoretical studies of the scandium carbide endohedral metallofullerene Sc2C2@C-82 and its carbene derivative - ir:ir-batch6-554733000:25:16 2015-07-04
Energy barrier for cyclopropylchlorocarbene rearrangement measured by direct observation of the carbene in laser flash spectroscopy - ir:ir-batch6-142028502:12:07 2015-07-04
Photolysis of 3-chloro-3-aryldiazirines in the presence of amines and allyl alcohol - ir:ir-batch6-139328705:51:33 2015-07-04
Measurement of the absolute rate of 1,2-hydrogen migration in benzylchlorocarbene - ir:ir-batch6-142330004:47:38 2015-07-04
The barrier for 1, 2-hydrogen shift in dialkyl carbenes - ir:ir-batch6-142828106:12:33 2015-07-05
Termolecular trapping of benzylchlorocarbene by methanol - ir:ir-batch6-145527611:32:43 2015-07-05
Kinetic and spectroscopic properties of carbene-diazirine ylides - ir:ir-batch6-137628717:15:17 2015-07-01
Laser flash photolysis studies on intra- and intermolecular reactions of some halocarbenes - ir:ir-batch6-138725911:13:51 2015-07-05
Synthesis of 3-substituted indolizines from the reaction of chlorocarbenes with 2-vinylpyridine - ir:ir-batch6-139926814:27:36 2015-07-03
Photochemical decomposition of pyrazoline produced in the reaction of C60 with Diazoadamantane - ir:ir-batch6-148527902:38:20 2015-07-03
Origin of the stereoselectivity of the intramolecular 1,2-hydrogen shift in singlet chlorocarbenes. A theoretical study - ir:ir-batch6-138631404:57:24 2015-07-05
A study of the vacuum pyrolysis of para-substituted diazoacetophenones with He(I) ultraviolet photoelectron spectroscopy - ir:ir-batch6-138129103:03:45 2015-07-04
Photo-labelling of C60 with 3-trifluoro-3-phenyldiazirine - ir:ir-batch6-554628008:01:03 2015-07-04
Isolation and characterization of a carbene derivative of La@C-82 - ir:ir-batch6-136728814:58:49 2015-07-03
Direct measurement of the energy barrier for 1,2-chlorine atom migration in α-methyl-α-chlorobenzyl (Chloro) crbene - ir:ir-batch6-140428207:40:49 2015-07-05
Electron spin resonance studies of diazirine anion radicals - ir:ir-batch6-144428319:46:50 2015-07-04
Kinetics of the oxidation of cyclohexene by thallium(II1) acetate - ir:ir-batch6-145125521:30:38 2015-07-04
Kinetics of the 1, 5‐dipolar cyclization of 2‐Vinylpyridinium ylides to Indolizines. Determination of rate parameters by laser flash photolysis - ir:ir-batch6-139129306:34:40 2015-07-04
Absolute rate constant for the reaction of benzylchlorocarbene with hydrogen chloride - ir:ir-batch6-141131818:26:28 2015-07-04
Benzylchlorocarbene: UV absorption spectrum, kinetics for 1,2-H migration and mechanism for reaction with acetic acid as determined by combined continuous and laser-flash photolysis - ir:ir-batch6-141656007:25:04 2015-07-05