Synthesis and reactivity of arenes coordinated to ...
|Title||Synthesis and reactivity of arenes coordinated to cyclopentadienyliron cations.|
|Author(s)||A. Abd-El-Aziz, S. Bernardin|
|Journal||Section Title: Organometallic and Organometalloidal Compounds, Coordination Chemistry Reviews|
|Abstract||Over the past few decades, there was tremendous interest in the chem. of arenes coordinated to transition metal moieties due to their applications in the fields of org. and polymer synthesis. The electrophilicity of coordinated arenes allows for reactions with a no. of C-, O-, N- and S-contg. nucleophiles. This review, with 314 refs., describes the synthesis and reactivity of both mono- and polyiron arene complexes. Spectroscopic and electrochem. methods for the characterization of these coordination compds. are presented. The important synthetic applications of arene cyclopentadienyliron complexes are also described. [on SciFinder(R)]|
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