A convenient synthesis of some arylated ...
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| Title | A convenient synthesis of some arylated phenylsulfonylacetonitriles and ethyl cyanoacetates using organoiron complexes. |
| Author(s) | A. Abd-El-Aziz, C. De Denus |
| Journal | Section Title: Benzene, Its Derivatives, and Condensed Benzenoid Compounds, Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999) |
| Date | 1993 |
| Volume | |
| Issue | 2 |
| Start page | 293 |
| End page | 298 |
| Abstract | Arylated phenylsulfonylacetonitriles, e.g., PhCH(CN)SO2Ph, and Et cyanoacetates, e.g., PhCH(CN)CO2Et, were prepd. by nucleophilic substitution of cyclopentadienyliron complexes of chloroarenes, e.g., I, with NCCH2R (R = SO2Ph, CO2Et) in the presence of potassium carbonate in DMF followed by photolysis. This synthesis is advantageous over all those previously reported and should be a practical route to a variety of alkanoic acid and heterocyclic precursors. [on SciFinder(R)] |
| ISSN | 0300-922X |
Using APA 6th Edition citation style.
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