Innovative approach to the synthesis of sulfides and ...

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Title Innovative approach to the synthesis of sulfides and their corresponding sulfones.
Author(s) A. Abd-El-Aziz, K. Epp, Y. Lei, S. Kotowich
Journal Section Title: Benzene, Its Derivatives, and Condensed Benzenoid Compounds, Journal of Chemical Research, Synopses
Date 1995
Volume
Issue 5
Start page 182
End page 183
Abstract Nucleophilic arom. substitution (SnAr) of cyclopentadienyliron-arene complexes with various aliph. or arom. dithiols followed by oxidn. and/or photolysis is presented as a viable route to the prepn. of the corresponding bis(sulfides) and bis(sulfones) in yields of 70-96%. The photochem. reaction of iron complexes I (R = H, alkyl, etc.; X = O, S; Cp = cyclopentadienyl) gave the sulfides II (same R, X). [on SciFinder(R)]
ISSN 0308-2342

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