The synthesis of new di(Cyclopentadienyliron) ...
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Citation
| Title | The synthesis of new di(Cyclopentadienyliron) complexes of polyaromatic ethers. |
| Author(s) | A. Abd-El-Aziz, D. Schriemer |
| Journal | Section Title: Organometallic and Organometalloidal Compounds, Inorganica Chimica Acta |
| Date | 1992 |
| Volume | 202 |
| Issue | 2 |
| Start page | 123 |
| End page | 125 |
| Abstract | Double nucleophilic substitution of 1,2-, 1,3-, or 1,4-(HO)2C6H4 with [(η5-C5H5)Fe(η6-C6H5Cl)]+ PF6- (anion assumed) and K2CO3 in THF/DMF afforded the corresponding bis(cyclopentadienyliron) arom. ether complexes I, isolated as PF6- salts. Compds. I and biphenyl analogs were prepd. in 70-95% yield. Cyclic voltammograms for all the complexes were obtained. All voltammograms reveal two redn. steps. Both redn. steps consist of two unresolved one-electron transfers, indicating an isolation of redox centers. [on SciFinder(R)] |
| DOI | 10.1016/S0020-1693(00)86826-7 |
| ISSN | 0020-1693 |
Using APA 6th Edition citation style.
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