Synthesis of oligomeric and polymeric ethers ...
|Title||Synthesis of oligomeric and polymeric ethers containing the Cp*Ru+ and CpFe+ metal moieties.|
|Author(s)||C. De Denus, L. Hoffa, E. Todd, A. Abd-El-Aziz|
|Journal||Section Title: Chemistry of Synthetic High Polymers, Journal of Inorganic and Organometallic Polymers|
|Abstract||A variety of homometallic (Cp*Ru+) and heterometallic (CpFe+-Cp*Ru+) oligomers with one to five metal moieties were prepd. in high yields (74-90%) via nucleophilic arom. substitution reactions. For the mixed metal systems, it is shown that the arrangement of the metal moieties along the backbone can be controlled. In addn., the synthesis of heterometallic polymers is described, along with their decomplexation and thermal properties. It was found that the thermal properties and soly. of the systems are greatly dependent on the linkages within the polymer backbone. [on SciFinder(R)]|
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