Laser flash photolysis studies on intra- and ...
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Citation
| Title | Laser flash photolysis studies on intra- and intermolecular reactions of some halocarbenes |
| Author(s) | M. Liu, R. Bonneau |
| Journal | Journal of the American Chemical Society |
| Date | 1996 |
| Volume | 118 |
| Issue | 34 |
| Start page | 8098 |
| End page | 8101 |
| Abstract | Laser flash photolysis studies on alpha-methylbenzylchlorodiazirine, n-propylchlorodiazirine, and isopropylchlorodiazirine have been carried out at low temperatures, ranging from 170 to 230 K. The present results, together with those previously obtained with benzylchlorodiazirine and methylchlorodiazirine, provide a direct measurement of the ''by-stander effect'' of alkyl substituents on the C atom in the alpha position of the carbene center. Intermolecular reactions of alpha-methylbenzylchlorocarbene and tetramelhylethylene in isooctane and methylcyclohexane have been measured but this reaction is shown to be too slow to measure by LFP in highly viscous decalin solvent. |
| ISSN | 0002-7863 |
Using APA 6th Edition citation style.
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