Direct measurement of the energy barrier for ...
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Citation
| Title | Direct measurement of the energy barrier for 1,2-chlorine atom migration in α-methyl-α-chlorobenzyl (Chloro) crbene |
| Author(s) | M. Liu, J. Chateauneuf |
| Journal | Journal of Physical Organic Chemistry |
| Date | 1992 |
| Volume | 5 |
| Issue | 5 |
| Start page | 285 |
| End page | 286 |
| Abstract | The first direct determination of a 1,2-chlorine atom shift in a chlorobenzylcarbene was achieved by nanosecond laser flash photolysis. Arrhenius activation parameters of E(act) = 3.39 +/- 0.14 kcal mol-1 and log [A(s-1)] = 10.98 +/- 0.14 were obtained for 1,2-chlorine migration in alpha-methyl-alpha-chlorobenzyl(chloro)carbene. The lifetime of this carbene is considerably longer than previously estimated and the measured E(act) is in excellent agreement with that determined by product analysis. |
| ISSN | 0894-3230 |
Using APA 6th Edition citation style.
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