6-Oxocyclohexa-2,4-dienylideneketene: A Highly ...
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| Title | 6-Oxocyclohexa-2,4-dienylideneketene: A Highly Reactive ?-Oxoketene |
| Author(s) | R. Liu, J. Lusztyk, M. McAllister, T. Tidwell, B. Wagner |
| Journal | Journal of the American Chemical Society |
| Date | 1998 |
| Volume | 120 |
| Issue | 25 |
| Start page | 6247 |
| End page | 6251 |
| Abstract | Abstract: The title ketene 2 has been generated by laser flash photolysis and observed in solution for the first time, using time-resolved infrared spectroscopy. The kinetics of the reactivity of 2 with H2O, MeOH, and Et2NH with relative reactivities of 1.0, 2.0, and 73 have been measured. These are the first direct measurements of the reactivities of a ketene with these different nucleophiles under the same conditions. Ab initio molecular orbital calculations indicate the hydration occurs by in-plane attack of the H2O molecule on the ketenyl carbonyl through a pseudopericyclic transition state with assistance by coordination to the keto-carbonyl. |
| DOI | 10.1021/ja980060t |
| ISSN | 0002-7863 |
Using APA 6th Edition citation style.
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