Kinetics of reactions of Schiff-base complexes of ...
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| Title | Kinetics of reactions of Schiff-base complexes of iron (II). Part 6. The preparation and kinetics of reactions of multidentate ligand complexes |
| Author(s) | M. Blandamer, J. Burgess, R. Haines, F. Mekhail, P. Askalini |
| Journal | Journal of the Chemical Society, Dalton Transactions |
| Date | 1978 |
| Volume | |
| Issue | 8 |
| Start page | 1001 |
| End page | 1008 |
| Abstract | Preparations of iron(II) complexes of bi-, tri-, quadri-, quinque-, and sexi-dentate Schiff bases are reported. The Schiff-base ligands are derived from pyridine-2-carbaldehyde, phenyl 2-pyridyl ketone, pyridine-2,6-dicarb-aldehyde. or 2,6-diacetylpyridine, and appropriate amines. All these complexes aquate in acid solution, and react with cyanide to give ternary iron(II)?cyanide?Schiff-base complexes. The kinetics of aquation of several of these Schiff-base complexes, and the kinetics of cyanide attack at all the complexes, are described, and reactivities are compared with those for analogous reactions of other iron(II) di-imine complexes. Solvent effects on the re-activity with cyanide of one of the complexes of the sexidentate Schiff bases in a range of binary aqueous mixtures are discussed. |
| DOI | 10.1039/DT9780001001 |
| ISSN | 1472-7773 |
Using APA 6th Edition citation style.
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