Does Gd@C82 Have an Anomalous Endohedral Structure? ...
|Title||Does Gd@C82 Have an Anomalous Endohedral Structure? Synthesis and Single Crystal X-ray Structure of the Carbene Adduct|
|Author(s)||T. Akasaka, T. Kono, Y. Takematsu, H. Nikawa, T. Nakahodo, T. Wakahara, M. Ishitsuka, T. Tsuchiya, Y. Maeda, M. Liu, K. Yoza, T. Kato, K. Yamamoto, N. Mizorogi, Z. Slanina, S. Nagase|
|Journal||Journal of the American Chemical Society|
|Abstract||Abstract: We report here the results on single crystal X-ray crystallographic analysis of the Gd@C82 carbene adduct (Gd@C82(Ad), Ad = adamantylidene). The Gd atom in Gd@C82(Ad) is located at an off-centered position near a hexagonal ring in the C2v-C82 cage, as found for M@C82 (M = Sc and La) and La@C82(Ad). Theoretical calculation also confirms the position of the Gd atom in the X-ray crystal structure.|
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