Synthesis and epoxidation of cis-enriched polydeltacyclene
Lautens, MarkAbd-El-Aziz, Alaa S.Schmidt, Gunther
Macromolecules
Journal Article
1990
23
10
2819
2821
10.1021/ma00212a038
Chemistry
Polydeltacylene (I) having >95% cis-configuration was prepd. by ring-opening metathesis polymn. in presence of ReCl5. Treatment of I with dimethyldioxirane gave quant. epoxidn., and polynorbornene exhibited similar behavior.
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