Intercalation of tetraazamacrocycles into molybdenum disulfide

Bissessur, Rabin
Haines, Robert I.
Bruning, R.

Journal of Materials Chemistry

Journal Article

2003

13

1

44

49

10.1039/B208237N

Chemistry

A series of intercalation compounds of tetraazamacrocycles in molybdenum disulfide have been synthesized using the exfoliation and restacking properties of LiMoS2. The sandwiched compounds were characterized by powder X-ray diffraction, thermogravimetric analyses, differential scanning calorimetry, and four-probe electrical conductivity measurements. The interlayer spacing of the intercalation compound was found to be dependent on the size of the macrocyclic ligand, indicating that the Show moreA series of intercalation compounds of tetraazamacrocycles in molybdenum disulfide have been synthesized using the exfoliation and restacking properties of LiMoS2. The sandwiched compounds were characterized by powder X-ray diffraction, thermogravimetric analyses, differential scanning calorimetry, and four-probe electrical conductivity measurements. The interlayer spacing of the intercalation compound was found to be dependent on the size of the macrocyclic ligand, indicating that the intercalated macrocycles are co-planar with the MoS2 sheets. Show less

Contact Publisher

green

NO_OBJ