Sulfur ylides generated from the reaction of adamantylidene and phenylcarbene with sulfur substrates

Romashin, Y. N.; Liu, Michael T. H.; Hill, B. T.; Platz, M. S.

Romashin, Y. N., Liu, M. T. H., Hill, B. T., & Platz, M. S. (2003). Sulfur ylides generated from the reaction of adamantylidene and phenylcarbene with sulfur substrates. Tetrahedron Letters, 44(34), 6519-6521.

Details

Title: Sulfur ylides generated from the reaction of adamantylidene and phenylcarbene with sulfur substrates
Author(s): Romashin, Y. N.
Liu, Michael T. H.
Hill, B. T.
Platz, M. S.
Source: Tetrahedron Letters
Genre: Journal Article
Date: 2003
Volume: 44
Issue: 34
Start Page: 6519
End Page: 6521
Department: Chemistry
Abstract: Reaction of adamantylidene and phenylcarbene with ethylthiol, ethylene dithiol, allylethylsulfide, allylphenylsulfide, and trimethylenesulfide involves the formation of a sulfur ylide intermediate, followed by H-migration, 2,3-sigmatropic shift, or ring opening to give sulfides. The sulfur ylide formed in the reaction of phenylcarbene with trimethylenesulfide is directly observed by laser flash photolytic techniques. (C) 2003 Elsevier Ltd. All rights reserved.
Romeo Colour: green
Check at UPEI
Statistics: views: 73

Robertson Library

Sulfur ylides generated from the reaction of adamantylidene and phenylcarbene with sulfur substrates

Primary tabs

Bookmarks:

About UPEI

Academics

Current Students

Apply to UPEI

Research