Sulfur ylides generated from the reaction of adamantylidene and phenylcarbene with sulfur substrates

Romashin, Y. N.; Liu, Michael T. H.; Hill, B. T.; Platz, M. S.

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Romashin, Y. N., Liu, M. T. H., Hill, B. T., & Platz, M. S. (2003). Sulfur ylides generated from the reaction of adamantylidene and phenylcarbene with sulfur substrates. Tetrahedron Letters, 44(34), 6519-6521.

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Title: Sulfur ylides generated from the reaction of adamantylidene and phenylcarbene with sulfur substrates
Author(s): Romashin, Y. N.
Liu, Michael T. H.
Hill, B. T.
Platz, M. S.
Source: Tetrahedron Letters
Genre: Journal Article
Date: 2003
Volume: 44
Issue: 34
Start Page: 6519
End Page: 6521
Department: Chemistry
Abstract: Reaction of adamantylidene and phenylcarbene with ethylthiol, ethylene dithiol, allylethylsulfide, allylphenylsulfide, and trimethylenesulfide involves the formation of a sulfur ylide intermediate, followed by H-migration, 2,3-sigmatropic shift, or ring opening to give sulfides. The sulfur ylide formed in the reaction of phenylcarbene with trimethylenesulfide is directly observed by laser flash photolytic techniques. (C) 2003 Elsevier Ltd. All rights reserved.
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Sulfur ylides generated from the reaction of adamantylidene and phenylcarbene with sulfur substrates

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