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Rapid hydrolysis of 2 ',3 '-cAMP with a Cu(II) complex

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Synthesis of protected guanidinium linked dinucleoside incorporable into an oligonucleotide using solid phase DNA methodology

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The synthesis of novel fully protected guanidinium linked dinucleoside for incorporation into oligonucleotide using solid-phase DNA synthesis methodology was developed. The three different protecting groups selected allow different deprotection conditions. (C) 1998 Elsevier Science Ltd. All rights r...

Rapid hydrolysis of RNA with a CU-II complex

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Solid-phase synthesis of deoxynucleic guanidine (DNG) oligomers and melting point and circular dichroism analysis of binding fidelity of octameric thymidyl oligomers with DNA oligomers

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Abstract: A practical solid-phase synthesis of deoxynucleic guanidine (DNG), a positively charged DNA backbone analogue, is reported. The nucleoside coupling step in the solid-phase synthesis of DNG involves the attack of a terminal 3'-amine upon an electronically activated 5'-carbodiimide to create...

Benzylchlorocarbene: UV absorption spectrum, kinetics for 1,2-H migration and mechanism for reaction with acetic acid as determined by combined continuous and laser-flash photolysis

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Eunicea fusca and Pseudopterogorgia elisabethae as a resource for bioactive diterpenes

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Natural products have long been recognized for their medicinal value in traditional medicine and remain an important component of modern drug discovery. Known for their immense structural diversity, natural products are secondary metabolites that often exhibit unique pharmacological properties. In t...