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Multifunctional macromolecules continue to attract attention. Here, three generations of a new family of bifunctional organoiron dendrimers are reported, which are synthesized from a redox-active organoiron complex, η6-dichlorobenzene-η5-cyclopentadienyl-iron(II). The facile chemistry of the compl...
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Nanocomposites containing ionically-conductive polymers are of interest due to potential applications as solid electrolytes for lithium–ion batteries. This paper reports intercalation of varying mole ratios of poly[oxy-methylene-(oxyethylene)] into lithium hectorite. The resulting nanocomposites w...
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Optoacoustic (OA) imaging is a new technique for cancer detection and non-invasive monitoring of cancer therapeutics. This technique is the combination of both optical and ultrasound modalities, in which tissue is irradiated with nanosecond laser pulses. The delivered optical energy is absorbed and ...
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Polyaniline, poly( N-methyl aniline), poly(2-ethyl aniline) and poly(2-propyl aniline) were intercalated into layered molybdenum diselenide by using the exfoliation/restacking property of LiMoSe. MoSe was reacted with n-butyllithium to form LiMoSe. The LiMoSe was exfoliated in N-methylformamide (NMF...
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Highlights: [•] Facile de-intercalating Na from NaFeO2. [•] Formation of layered sodium hydrogen carbonate hydrate. [•] Intercalation chemistry on layered sodium hydrogen carbonate hydrate.
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Poly(ethylene glycol) functionalized with an amino group (PEG-amine) was synthesized and characterized by proton NMR and FTIR spectroscopy. The polymer was complexed with lithium triflate (LiOTf) in varying ratios, and it was found that the composition (PEG-amine)8.0LiOTf exhibited a maximum ionic c...
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MoSe2 has been encapsulated with a variety of guest species. This was achieved by first treating the MoSe2 with an excess of n-BuLi to form the lithiated phase of MoSe2 (LixMoSe2). The LixMoSe2 exfoliates readily in water or NMF to yield single layers of MoSe2. Addition of solutions of polymers, org...
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Novel (amide–imide)-silica composites that can be used to enhance the mechanical properties of high performance polymers have successfully been synthesized by a sol–gel process. In a first step, a dimer containing two chemically pre-formed imide rings has been synthesized and fully characterized...
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Novel intercalation compounds of poly(ethylene oxide), poly(vinylpyrrolidone), poly(oligo ethylene glycol)-oxalate], polyoxymethylene-(oxyethylene)] and polybis-(methoxyethoxyethoxy)phosphazene] into SnS2 have been prepared. This was achieved by using the exfoliating and re-stacking properties of Li...
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Intercalation compounds of polyethylene oxide, polyvinylpyrrolidone, methyl cellulose, poly[oxymethylene-(oxyethylene)] and poly[oligo(ethylene glycol oxalate)] into graphite oxide (GO) have been synthesized. The forces of attraction between the polymers and GO are primarily dipole?dipole and/or hyd...