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Pendant-arm tri- and tetraazamacrocycles
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This paper reviews the synthesis of pendant-arm macrocycles, and the structure and some properties of their first row transition metal complexes. The article covers the period 1997 to 2000, since a thorough review had previously been published, to 1997. The focus of this paper is on tri- and tetraaz...
Structure of tetraphenylarsonium tricyano-2,2 ',6 ',2 ''-terpyridyl-ferrate(II), AsPh4[Fe-II(terpy)(CN)(3)]; and kinetics of oxidation of the complex anion by peroxodisulfate in water and in binary aqueous mixtures
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The structure of the title compound has been determined by X-ray crystallography. The octahedral arrangement of ligands about the iron(II) centre is somewhat distorted, with the axial NC-Fe-CN bond angle being 174.3(4)degrees. The oxidation of the tricyano-2,2',6',2 '-terpyridylferrate(II) anion by ...
Activation Volumes for Peroxodisulfate Oxidation of Cobalt(iii), Iron(ii) and Nickel(ii) Complexes
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Dependences of rate constants on pressure (in aqueous solution up to 1.25 kbar) are reported for peroxodisulphate oxidation of hexacyanoferrate(TI), tris(2,2'-bipyridyl)iron(II), tris(l,10-phenanthroline)iron(II), bis(l,4,7-triazacyclononane)nickel(II) and bis(l,2-ethanediamine)cysteinatocobalt(III)...