First ring-opening metathesis polymerization of ...

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Title First ring-opening metathesis polymerization of norbornenes containing cationic iron moieties.
Author(s) A. S. Abd-El-Aziz, L. J. May, J. A. Hurd, R. M. Okasha
Journal Journal of Polymer Science ,
Date 2001
Volume 39
Issue 16
Start page 2716
End page 2722
Abstract Novel polynorbornenes containing cationic cyclopentadienyliron moieties pendent to the polymer side chains were prepared via polymerization of metallated norbornene monomers using Grubbs' catalyst. Thermogravimetric analysis of the organometallic polymers showed two weight loss steps: the first at 200–230 °C represented loss of the metallic moieties, followed by decomposition of the polymer backbone between 400 and 450 °C. Cyclic voltammetric studies of the organometallic polymers showed one reversible reduction process.
DOI 10.1002/pola.1249

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