Synthesis of aromatic nitriles via the temporary ...



Title Synthesis of aromatic nitriles via the temporary complexation of nitroarenes to the cationic cyclopentadienyliron moiety.
Author(s) Alaa S. Abd-El-Aziz, Waleed Boraie, Nicole T. Gavel
Journal Organometallics,
Date 1999
Volume 18
Issue 8
Start page 1562
End page 1564
Abstract Cyanide addition to cyclopentadienyliron complexes of substituted nitroarenes produced nitrile adducts where the cyano group added in the ortho position with respect to the nitro group. Cleavage of the cyclopentadienyliron moiety via oxidative demetalation with DDQ led to the isolation of functionalized aromatic nitriles in good yields.
DOI 10.1021/OM981022L

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