Neutral and cationic cyclopentadienyliron ...



Title Neutral and cationic cyclopentadienyliron macromolecules containing arylazo chromophores.
Author(s) Alaa S. Abd-El-Aziz, Rawda M. Okasha, Patrick O. Shipman, Tarek H. Afifi
Journal Macromolecular Rapid Communications,
Date 2004
Volume 25
Issue 16
Start page 1497
End page 1503
Abstract Summary: A new class of macromolecules containing neutral and cationic organoiron moieties with arylazo chromophores in their backbones has been prepared. Photolysis of these polymers resulted in the removal of the cationic iron moieties leading to new polyferrocenes with azo dyes in their backbones. UV-vis studies showed λmax around 419 nm in DMF with a bathochromic shift to around 530 nm upon the addition of HCl.
DOI 10.1002/marc.200400218

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