Redox-active ...



Title Redox-active η6-arene-η5-cyclopentadienyliron-containing macromolecules.
Author(s) Alaa S. Abd-El-Aziz, Patrick O. Shipman, Sarrah A. Carruthers, Rawda M. Okasha, Erin K. Todd
Journal Section Title: Physical Properties of Synthetic High Polymers, PMSE Preprints
Date 2006
Volume 95
Start page 158
End page 159
Abstract There has been tremendous interest in organoiron macromols. This interest stems from their application as chem. sensors, electrocatalysts, modified electrodes and photo-active mol. devices. Herein, we report the synthesis and characterization of a no. of different classes of organoiron macromols. contg. η6-arene-η5--cyclopentadienyliron complexes, and ferrocene. The electrochem. behavior of these materials has been investigated and showed the redn. of the cationic iron moieties and the oxidn. of the ferrocene moieties. The synthesis properties and the electrochem. studies of these iron-contg. macromols. will be presented. [on SciFinder(R)]

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