Design of four-arm organoiron macromolecules ...



Title Design of four-arm organoiron macromolecules containing azo chromophores.
Author(s) Alaa S. Abd-El-Aziz, Elizabeth A. Strohm, Man Ding
Journal Polymer Preprints ,
Date 2011
Volume 52
Issue 2
Start page 803
End page 804
Abstract Various four-arm organoiron macromols. contg. different azo dye moieties have been prepd. via metal-mediated nucleophilic arom. substitutions and ester condensation reactions. The synthesis of a four-arm organoiron star contg. aryl- and hetaryl-azo chromophores (7) and a cross-linked azo dye-contg. organoiron macromol. (10) are reported as two example models. NMR spectroscopy was used to characterize the reported complexes, with the exception of the cross-linked star (10). UV-vis anal. of azo dyes 4, 5, and 6 were reported as examples.

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