A novel approach to the synthesis of some ...
|Title||A novel approach to the synthesis of some 2-arylalkanoic acid esters.|
|Author(s)||A. Abd-El-Aziz, S. Tesfalidet, C. de Denus, K. Lezynska|
|Journal||Section Title: Benzene, Its Derivatives, and Condensed Benzenoid Compounds, Synthetic Communications|
|Abstract||A novel route to the synthesis of some 2-arylalkanoic acid esters has been achieved. Arom. nucleophilic substitution of various arenecyclopentadienyliron complexes, e.g., I (R = Cl, R1 = H, 3-, 4-Me) with Et ethylacetoacetate and Et methylacetoacetate produced the alkanoic acid ester complexes I (R = CHR2CO2Et, R2 = Me, Et). Photolysis of these complexes resulted in the liberation of the free esters II in good yields. [on SciFinder(R)]|
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