|Author(s)||A. Abd-El-Aziz, E. Todd|
|Journal||Section Title: Chemistry of Synthetic High Polymers, Coordination Chemistry Reviews|
|Abstract||In this review, organoiron polymers are classified according to their structural make-up. The synthesis and characterization of oligomers and polymers contg. dienes and cyclobutadiene rings coordinated to iron tricarbonyl moieties are described. This is followed by a thorough investigation of ferrocene-based polymers. The ferrocenyl units are found in the polymer main and side chains, and a wide variety of these organoiron polymers and their properties are examd. Polymers contg. cyclopentadienyliron tricarbonyl complexes in their backbones and side chains are also described. Cationic Î·6-arene-Î·5-cyclopentadienyliron complexes have been incorporated into polymeric materials where the iron moieties are pendent to the main or side chains. The final class of organoiron polymers includes the iron-acetylides; these polymers are unique among the other examples described since the iron complexes are Ïƒ-bonded to the org. backbones of the polymers. [on SciFinder(R)]|
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