Polymerization of methacrylates containing cationic ...
|Title||Polymerization of methacrylates containing cationic cyclopentadienyliron moieties.|
|Author(s)||A. Abd-El-Aziz, E. Todd, G. Ma, J. DiMartino|
|Journal||Section Title: Chemistry of Synthetic High Polymers, Journal of Inorganic and Organometallic Polymers|
|Abstract||A novel approach to the synthesis of polymethacrylates contg. cationic cyclopentadienyliron moieties pendent to their side chains was accomplished via the use of Ï€-coordinated organoiron complexes. The complexed methacrylates were polymd. in the presence of AIBN to give sol. organoiron polymethacrylates in 80-90% yields. Photolytic demetalation of the organoiron polymers allowed for the isolation of their org. analogs whose wt. av. mol. wts. ranged from 48.500 to 68.300. [on SciFinder(R)]|
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